28115-04-0

Basic information

• Product Name: 1-methoxy-4-(3-methylbut-1-en-2-yl)benzene
• Synonyms: 1-methoxy-4-(3-methylbut-1-en-2-yl)benzene
• CAS NO: 28115-04-0
• Molecular Weight: 176.258
• Mol File: 28115-04-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-methoxy-4-(3-methylbut-1-en-2-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-4-(3-methylbut-1-en-2-yl)benzene(28115-04-0)
• EPA Substance Registry System: 1-methoxy-4-(3-methylbut-1-en-2-yl)benzene(28115-04-0)

Safety Data

• Hazardous Substances Data: 28115-04-0(Hazardous Substances Data)

Upstream product

• 28114-95-6 3-methyl-2-(4-methoxyphenyl)butan-2-ol 
• 563-45-1 3-Methyl-1-butene 
• 2040-20-2 4-methoxyisobutyrophenone 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 874-90-8 4-methoxybenzonitrile 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 10288-13-8 1,2-dibromo-3-methylbutane 
• 5720-07-0 4-methoxyphenylboronic acid 
• 17580-45-9 3-(4-methoxyphenyl)-2,2-dimethylbut-3-enoic acid 

Downstream Products

• 35144-47-9 C₁₂H₁₇O⁽¹⁺⁾ 
• 91881-09-3 4-(1,2-dimethyl-propyl)-anisole 

Relevant articles and documents

Electrochemical [4+2] Annulation-Rearrangement-Aromatization of Styrenes: Synthesis of Naphthalene Derivatives

We report the first electrochemical strategy to synthesize functionalized naphthalene derivatives through [4+2] annulation—rearrangement–aromatization from styrenes under mild conditions. The electrolysis does not require metals, oxidants and high valence substrates, indicating the atom and step-economy ideals. The dehydrodimer produced through [4+2] cycloaddition of 4-methoxy α-methyl styrene is isolated and proved to be the key intermediate for the following oxydehydrogenation to form carbon cation, which undergoes rearrangement–aromatization to afford the final products. This reaction represents a powerful access to construct multi-substituted naphthalene blocks in a single step.

Enantiopure C1-symmetric bis(imino)pyridine cobalt complexes for asymmetric alkene hydrogenation

Enantiopure C1-symmetric bis(imino)pyridine cobalt chloride, methyl, hydride, and cyclometalated complexes have been synthesized and characterized. These complexes are active as catalysts for the enantioselective hydrogenation of geminal-disubstituted olefins.

Stannous chloride dihydrate: A new catalyst for the tetrahydropyranylation of alcohols

Catalytic Stannous chloride dihydrate in polar aprotic solvents like chloroform efficiently catalyse the tetrahydropyranylation of alcohols in a short time under mild conditions.