28377-92-6

Basic information

• Product Name: Decaborane-dimethylsulfidate
• Synonyms: Decaborane-dimethylsulfidate
• CAS NO: 28377-92-6
• Molecular Formula: C₄H₂₄B₁₀S₂
• Molecular Weight: 236.39
• Mol File: 28377-92-6.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Decaborane-dimethylsulfidate(CAS DataBase Reference)
• NIST Chemistry Reference: Decaborane-dimethylsulfidate(28377-92-6)
• EPA Substance Registry System: Decaborane-dimethylsulfidate(28377-92-6)

Safety Data

• Hazardous Substances Data: 28377-92-6(Hazardous Substances Data)

Upstream product

• 75-18-3 dimethylsulfide 
• 69943-44-8 1,5'-bi(nido-decaboranyl) 
• 20739-95-1 6-chloro decaborane⁽¹⁴⁾ 
• 17702-41-9 nido-decaborane 

Downstream Products

• 72765-39-0 9-cyclohexenyl-5-(dimethyl sulfide)-nido-decaborane⁽¹¹⁾ 
• 1447813-56-0 1-ferrocenyl-2-[4-(methoxycarbonyl)phenyl]-1,2-dicarba-closo-dodecaborane 
• 1447813-54-8 1-ferrocenyl-2-phenyl-1,2-dicarba-closo-dodecaborane 
• 1021495-30-6 6,9-(1,4-bis[β-(4-pyridyl)vinyl]benzene)2-arachno-B10H12 
• 1021495-32-8 N,N'-bis[9-Me2S-arachno-B10H12-6-yl](1,4-bis[β-(4-pyridyl)vinyl]benzene) 
• 72765-44-7 9-cyclohexyl-5⁽⁷⁾-(dimethyl sulfide)-nido-decaborane⁽¹¹⁾ 
• 17702-41-9 nido-decaborane 
• 75309-24-9 [7,7-(PMe₂Ph)2-nido-7-PtB₁₀H₁₂] 
• 96029-10-6 8-chloro-7,7-bis(dimethylphenylphosphine)-nido-7-platinaundecaborane 
• 101943-92-4 B₁₀H₁₂(P(CH₃)2(C₆H₅))2 

Relevant articles and documents

Macropolyhedral boron-containing cluster chemistry. A synthetic approach via the auto-fusion of [6,9-(SMe2)2-arachno-B 10H12]

In an attempt to build up borane-based multicluster assemblies, thermolysis of [6,9-(SMe2)2-arachnoB10H 12] 1 in inert hydrocarbon solution, followed by chromatographic separation, has resulted in the isolation not only of the previously established single-cluster product from this reaction, [5-(SMe 2)-nido-B10H12] 2 (30%), but also the two two-cluster species [6,9-(SMe2)2-arachno-B 10H11-l-(6′-nido-B10H13)] 3 (20%) and [l,6′-(nido-B10H13)2] 6 (ca. 0.5%) and the two three-cluster species [6,9-(SMe2) 2-arachno-B10H10-l,5-(6′-nido-B 10H13)2] 4 (5%), characterized crystallographically, and [6,9-(SMe2)2-arachno-B 10H10-l,3-(6′-nido-B10H 13)2] 5 (2)-nido-B 10H12] 2 is also presented. The feasibility of the stability of species resulting from multiple adjacent substitution of nido-decaboranyl units on the [6,9-(SMe2)2-arachno-B 10H12] skeleton is tested by DFT calculations. In an extension, to attempt the use of pre-a-linked two-cluster compounds as starting substrates, two-cluster [5-(SMe2)-4-(2′-nido-B 10H13)-nido-B10H11] 7 (0.6%) has been isolated from the reaction of SMe2 with [1,5′-(nido-B 10H13)2], other identified products being compound 1 (39%) and compound 3 (10.5%). The Royal Society of Chemistry 2006.