290825-97-7

Basic information

• Product Name: 2-(3-trimethylsilyl-prop-2-ynyl)-cyclohexanone
• Synonyms: 2-(3-trimethylsilyl-prop-2-ynyl)-cyclohexanone
• CAS NO: 290825-97-7
• Molecular Weight: 208.376
• Mol File: 290825-97-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-(3-trimethylsilyl-prop-2-ynyl)-cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3-trimethylsilyl-prop-2-ynyl)-cyclohexanone(290825-97-7)
• EPA Substance Registry System: 2-(3-trimethylsilyl-prop-2-ynyl)-cyclohexanone(290825-97-7)

Safety Data

• Hazardous Substances Data: 290825-97-7(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 10424-93-8 N'-cyclohexylidene-N,N-dimethyl-hydrazine 
• 38002-45-8 3-bromo-1-(trimethylsilyl)-1-propyne 

Downstream Products

• 1323770-18-8 C₁₉H₂₀O₂ 
• 1323770-73-5 C₁₉H₁₇⁽²⁾H₃O₂ 
• 19823-75-7 2-(2-propynyl)cyclohexanone 
• 93026-61-0 1-benzyl-2-methyl-4,5,6,7-tetrahydro-1H-indole 

Relevant articles and documents

Pyrrole synthesis catalyzed by AgOTf or cationic Au(I) complexes

Either silver trifluoromethanesulfonate or a mixture of gold(I) chloride, silver trifluoromethanesulfonate, and triphenylphosphine catalyze the formation of pyrroles from substituted β-alkynyl ketones and amines. The reactions proceed by using 5 mol % of catalyst with yields of isolated pyrroles ranging from 13% to 92%. Sixteen examples are used to compare the effectiveness of each catalyst.