29173-12-4Relevant articles and documents
The chemistry of borylstannanes: Oxidative addition to palladium species and its application to palladium-catalyzed borylstannation of alkynes
Onozawa, Shun-Ya,Hatanaka, Yasuo,Sakakura, Toshiyasu,Shimada, Shigeru,Tanaka, Masato
, p. 5450 - 5452 (1996)
cis addition of the borylstannanes Me3SnB-[NMe(CH2CH2)NMe] (1) and Me3SnB(NEt2)2 (4) across alkynes was efficiently catalyzed at room temperature or 80°C by Pd(PPh3)4,
Boron-nitrogen compounds. XXXIV. Preparation and some properties of 2-halo-1,3,2-diazaboracycloalkanes
Wang, Tai-Tzer,Busse, Paul J.,Niedenzu, Kurt
, p. 2150 - 2152 (2008/10/08)
A series of 2-halo-1,3,2-diazaboracycloalkanes has been prepared by (a) the interaction of trialkylamine-trihaloboranes with alphatic α,ω-diamines, (b) displacement of dimethylamino groups of 2-dimethylamino-1,3,2-diazaboracycloalkanes with halogen through interaction with boron trihalides, and (c) a transhalogenation reaction. The 2-halo-1,3,2-diazaboracycloalkanes are thermally rather stable but are very reactive toward moisture and oxygen. The boron-bonded halogen is readily replaced by organic groups through interaction with Grignard reagents. All compounds have a characteristic BN absorption in the 1510-1540-cm-1 region of their infrared spectra and the proton magnetic resonance spectra are consistent with their structure. In the mass spectra, the parent peaks P+ are generally less abundant than the (P - 1)+ peaks.