29949-93-7Relevant articles and documents
Tandem radical nitrile transfer-cyclization reactions of 1,3- dioxane-4-nitriles: Synthesis of spirocyclic systems
Rychnovsky, Scott D.,Swenson, Sonja S.
, p. 16489 - 16502 (1997)
Reduction of remote halogen substituents with n-Bu3SnH leads to efficient 1,4- and 1,5-nitrile transfer from 1,3-dioxane-4-nitriles and subsequent stereoselective reduction. These radical-transfer reactions provide a mild alternative to the Li/
Rhodium-catalyzed vinylcyclopropanation/cyelopentenation of strained alkenes via a sequential carborhodation process
Tseng, Nai-Wen,Lautens, Mark
supporting information; experimental part, p. 2521 - 2526 (2009/08/07)
A rhodium-catalyzed reaction of dienylboronate esters with alkenes is described. Strained bicyclic alkenes show the highest reactivity toward the rhodium-catalyzed addition of the dienylboronate esters. Depending on the substitution pattern of dienylboron
EPOTHILONE DERIVATIVES
-
Page/Page column 19-20; 45-46, (2010/02/14)
Epothilone derivatives of Formula (I) and their use as a pharmaceutical.