3005-62-7

Basic information

• Product Name: BZ-HIS-OME
• Synonyms: BZO-HIS-OME;BZ-HIS-OME;BZ-HISTIDINE-OME;N-ALPHA-BENZOYL-L-HISTIDINE METHYL ESTER;Bz-L-His-OMe;methyl 2-(benzoylamino)-3-(3H-imidazol-4-yl)propanoate;Nα-Benzoyl-L-histidine methyl ester≥ 99% (Elemental analysis)
• CAS NO: 3005-62-7
• Molecular Formula: C₁₄H₁₅N₃O₃
• Molecular Weight: 273.29
• Product Categories: Amino Acid Derivatives;Amino Acids
• Mol File: 3005-62-7.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 601.7 °C at 760 mmHg
• Flash Point: 317.7 °C
• Appearance: /
• Density: 1.268 g/cm³
• Vapor Pressure: 1.97E-14mmHg at 25°C
• Refractive Index: 1.588
• Storage Temp.: Store at RT.
• CAS DataBase Reference: BZ-HIS-OME(CAS DataBase Reference)
• NIST Chemistry Reference: BZ-HIS-OME(3005-62-7)
• EPA Substance Registry System: BZ-HIS-OME(3005-62-7)

Safety Data

• Hazardous Substances Data: 3005-62-7(Hazardous Substances Data)

Usage

Chemical Properties

White powder

InChI:InChI=1/C14H15N3O3/c1-20-14(19)12(7-11-8-15-9-16-11)17-13(18)10-5-3-2-4-6-10/h2-6,8-9,12H,7H2,1H3,(H,15,16)(H,17,18)

Upstream product

• 72318-53-7 N^α-benzoyl-N^Im-tosyl-L-histidine methyl ester 
• 98-88-4 benzoyl chloride 
• 4467-54-3 histidine methyl ester hydrochloride 
• 4467-54-3 l-histidine methyl ester dihydrochloride 
• 65-85-0 benzoic acid 
• 1015244-09-3 (Z)-2-benzamido-4⁽⁵⁾-N-imidazolylpropenoic acid methyl ester 
• 67-66-3 chloroform 
• 56-40-6 glycine 
• 35166-50-8 1,N^α-dibenzoyl-histidine methyl ester 
• 67-56-1 methanol 
• 5354-94-9 N-benzoyl-L-histidine 

Downstream Products

• 108839-11-8 1-acetyl-N^α-benzoyl-histidine-methyl ester 
• 102238-61-9 1-benzenesulfonyl-N^α-benzoyl-L-histidine-methyl ester 
• 97485-18-2 4-(1⁽³⁾H-imidazol-4-ylmethyl)-2-phenyl-4H-oxazol-5-one 
• 194797-41-6 N-[(S)-1-hydroxymethyl-2-(1⁽³⁾H-imidazol-4-yl)-ethyl]-benzamide 
• 24676-31-1 N^α-benzoyl-L-histidine amide 
• 125039-07-8 (S)-2-Benzoylamino-3-[1-(4-nitro-benzenesulfonyl)-1H-imidazol-4-yl]-propionic acid methyl ester 
• 35166-51-9 methyl ester of N^α-benzoyl-N^?-methyl-L-histidine 
• 65096-22-2 (-)-N(?)-methyl-N(α)-benzoyl-L-histidinol 
• 4836-52-6 (S)-histidinol 
• 873785-01-4 [(benzoyl)-His(n-propyl)2-(OMe)]Br 
• 87867-08-1 N(α)-benzoyl-N(τ)-(2-hydroxypropyl)histidine methyl ester 
• 87867-06-9 N(α)-benzoyl-N(τ)-(2-oxopropyl)histidine methyl ester 
• 87867-07-0 (S)-2-Benzoylamino-3-[3-(2-oxo-propyl)-3H-imidazol-4-yl]-propionic acid methyl ester 
• 72318-53-7 N^α-benzoyl-N^Im-tosyl-L-histidine methyl ester 

Relevant articles and documents

Functional ionic liquid mediated synthesis (FILMS) of dihydrothiophenes and tacrine derivatives

Natural amino acid-based functional ionic liquid [Bz-His(n-propyl) 2-OMe+Br-] promoted diastereoselective synthesis of dihydrothiophenes is described. Further this functional ionic liquid was efficiently utilized to form t

Histidine and deuterium labelled histidine by asymmetric catalytic reduction with gaseous H2 or D2; the role of strong non-coordinating acids

An efficient and convenient route for the preparation of natural and unnatural histidine by asymmetric hydrogenation with rhodium-phosphine complexes is described. The reductions were performed in the presence of HBF4 to generate an essential imidazolyl cation. Stereoselective incorporation of D2 in the α,β-positions was obtained by catalytic deuteration in the presence of MeOD.

A Simple and Mild Method for the Removal of the NIm-Tosyl Protecting Group

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