30089-54-4Relevant articles and documents
Air oxidative radical hydroxysulfurization of styrenes leading to β-hydroxysulfides
Zhou, Shao-Fang,Pan, Xiangqiang,Zhou, Zhi-Hao,Shoberu, Adedamola,Zou, Jian-Ping
, p. 3682 - 3687 (2015)
Air oxidative radical hydroxysulfurization of styrenes initiated by 0.5 mol % of tert-butyl hydroperoxide with arylthiols is described, and a new type of difunctionalization of alkenes was achieved.
Catalyst-Free Difunctionalization of Activated Alkenes in Water: Efficient Synthesis of β-Keto Sulfides and Sulfones
Wang, Huamin,Wang, Guangyu,Lu, Qingquan,Chiang, Chien-Wei,Peng, Pan,Zhou, Jiufu,Lei, Aiwen
, p. 14489 - 14493 (2016/10/03)
Difunctionalization of activated alkenes, a powerful strategy in chemical synthesis, has been accomplished for direct synthesis of a series of β-keto sulfides and β-keto sulfones. The transformation, mediated by O2, proceeds smoothly in water and without any catalyst. Prominent advantages of this method include mild reaction conditions, purification simplicity, and gram-scale synthesis, underlining the practical utility of this methodology.