30670-30-5

Basic information

• Product Name: 1H,1H,2H,2H-PERFLUORODECYLAMINE
• Synonyms: 1H,1H,2H,2H-PERFLUORODECYLAMINE;1H,1H,2H,2H-Perfluorodecylamine 99%;1H,1H,2H,2H-Perfluorodecylamine99%;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecylamine;2-(Perfluorooctyl)ethylamine;1H,1H,2H,2H-Heptadecafluorodecylamine 97%;2-(Perfluorooct-1-yl)ethylamine, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecylamine
• CAS NO: 30670-30-5
• Molecular Formula: C₁₀H₆F₁₇N
• Molecular Weight: 463.13
• Mol File: 30670-30-5.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 73 °C
• Flash Point: 74.1°C
• Appearance: /
• Density: 1.595g/cm³
• Vapor Pressure: 0.792mmHg at 25°C
• Refractive Index: 1.3
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• Solubility: Ethanol (Slightly), Methanol (Slightly)
• PKA: 8.56±0.10(Predicted)
• CAS DataBase Reference: 1H,1H,2H,2H-PERFLUORODECYLAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: 1H,1H,2H,2H-PERFLUORODECYLAMINE(30670-30-5)
• EPA Substance Registry System: 1H,1H,2H,2H-PERFLUORODECYLAMINE(30670-30-5)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• HazardClass: IRRITANT
• Hazardous Substances Data: 30670-30-5(Hazardous Substances Data)

Usage

Uses

1H,1H,2H,2H-Perfluorodecylamine can be used as self-assembled monolayer (SAM) in organic LEDs

InChI:InChI=1/C10H6F17N/c11-3(12,1-2-28)4(13,14)5(15,16)6(17,18)7(19,20)8(21,22)9(23,24)10(25,26)27/h1-2,28H2

Upstream product

• 507-63-1 1-iodoheptadecafluorooctane 
• 2043-53-0 2-(n-perfluorooctyl)ethyl iodide 
• 57642-98-5 methyl-2-propen-3-ol 
• 121177-79-5 1-azido-1H,1H,2H,2H-perfluorodecane 

Downstream Products

• 688063-72-1 Boc-Lys(Z)-O-decyl(F₁₇) 
• 1325213-17-9 H₂N-Lys(Z)-O-decyl(F₁₇) 
• 1351283-11-8 C₃₈H₄₄F₂₀N₆O₁₁ 
• 1351283-10-7 C₃₂H₃₃F₂₀N₅O₈ 
• 1351283-09-4 C₂₆H₂₂F₂₀N₄O₅ 
• 1239023-31-4 C₂₆H₁₅F₁₇N₂O₄ 
• 1182707-56-7 N-(1H,1H,2H,2H-perfluorodecyl)-4,5-dimethyl-2-nitroaniline 
• 921926-97-8 N-benzyl-N-1H,1H,2H,2H-perfluorodecane 
• 921927-02-8 N-1H,1H,2H,2H-perfluorodecanebenzylamide 

Relevant articles and documents

Design, synthesis and preliminary biological evaluations of novel amphiphilic drug carriers

The synthesis of a new fluorocarbon amphiphilic drug carrier is described. A polyfunctional amino acid endowed with a fluorocarbon chain and a sugar moiety providing the amphiphilic character constitutes the central element of this structure. A 14/s

NMR and fluorescence studies of the self-association behavior of an amphiphilic polyanion bearing hydrocarbon and fluorocarbon hydrophobes

The association behavior of the terpolymers of sodium 2-acrylamido-2- methylpropanesulfonate (NaAMPS), N-dodecylmethacrylamide (DodMAm), and N-(2-(perfluorooctyl)ethyl)methacrylamide (PFOEMAm) (A/H(x)/F(y)) and their reference copolymers of NaAMPS and PFOEMAm (A/F(y)) was characterized using 19F and 1H NMR, steady state fluorescence, and dynamic light scattering techniques in water (or D2O) containing 0.1 M NaCl. The terpolymers formed micelle-like aggregates where hydrophobic microdomains are formed by hydrophobic associations among the perfluorooctylethyl (PFOE) and dodecyl (Dod) groups, the PFOE group exhibiting a stronger tendency for interpolymer association than the Dod groups. A careful analysis of the characterization data led to a conclusion that the hydrophobic microdomain formed from the terpolymer is microscopically phase separated into the fluorocarbon phase and hydrocarbon phase.

Convenient synthesis of 6,6-bicyclic malonamides: A new class of conformationally preorganized ligands for f-block ion binding

A general synthetic approach was developed for the preparation of a series of 6,6-bicyclic malonamides, a class of ligands that provide a preorganized binding site for f-block ions (particularly trivalent lanthanides). The approach described is convenient to introduce a variety of functional groups at the amide nitrogens to tune the properties of the ligand without altering the preorganized binding. Each of the ten derivatives (that represent a range of functionality, including R = alkyl, hydroxy, phenyl, ester, perfluorocarbon) reported here derives from a single, readily prepared dialdehyde intermediate. This intermediate is converted to the final products via reductive amination with an appropriately functionalized benzylamine, followed by hydrogenolysis and lactam formation. Because derivatization occurs late in the synthesis, the approach is general, requiring only modification of the purification procedures for each new derivative. To aid in the purification of the bicyclic malonamides, we report a novel complexation-based purification method that takes advantage of the high affinity of the ligand for f-block metals.