30780-30-4

Basic information

• Product Name: 2-Butanone, 4-[4-(dimethylamino)phenyl]-
• CAS NO: 30780-30-4
• Molecular Formula: C12H17NO
• Molecular Weight: 191.273
• Mol File: 30780-30-4.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 4-[4-(dimethylamino)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 4-[4-(dimethylamino)phenyl]-(30780-30-4)
• EPA Substance Registry System: 2-Butanone, 4-[4-(dimethylamino)phenyl]-(30780-30-4)

Safety Data

• Hazardous Substances Data: 30780-30-4(Hazardous Substances Data)

Upstream product

• 100-10-7 4-dimethylamino-benzaldehyde 
• 78-94-4 methyl vinyl ketone 
• 121-69-7 N,N-dimethyl-aniline 
• 598-32-3 2-hydroxy-3-butene 
• 586-77-6 4-bromo-N,N-dimethylaniline 
• 29546-14-3 4-((1H-benzo[d][1,2,3]triazol-1-yl)methyl)-N,N-dimethylaniline 
• 123-54-6 acetylacetone 
• 5432-53-1 4-p-dimethylaminophenyl-3-buten-2-one 
• 590-90-9 1-Hydroxy-3-butanone 

Downstream Products

• 81580-13-4 5-{2-[3-(4-Dimethylamino-phenyl)-1-methyl-propylamino]-1-hydroxy-ethyl}-2-hydroxy-benzamide 
• 13026-64-7 <3-(4-Dimetylamino-phenyl)-1-methyl-propyl>-<3,3-diphenylpropyl>-amin 

Relevant articles and documents

Gold-catalyzed hydroarylation of alkenes with dialkylanilines

Anti-Bredt di(amino)carbene supported gold(I) chloride complexes are readily prepared in two steps from the corresponding isocyanide complexes. In the presence of KB(C6F5)4as chloride scavenger, they promote the unprecedented hydroarylation reaction of alkenes with N,N-dialkylanilines with high para-selectivity. The latter are challenging arenes for Friedel-Craft reactions, due to their high basicity.

Michael Additions Catalyzed by a β-Diketiminate-Supported Aluminum Complex

A β-diketiminate-supported aluminum bistriflate complex (DipLAl(OTf)2·Na[BArCl4]; DipL = CH(CMe)2(N-C6H3-iPr2)2; Tf = O2SCF

A Hantzsch Amido Dihydropyridine as a Transfer Hydrogenation Reagent for α,β-Unsaturated Ketones

An improved synthesis of the bis-methylamido Hantzsch dihydropyridine is described. The Hantzsch amide is demonstrated to be an effective transfer hydrogenation reagent using α,β-unsaturated ketones as the test case. Unreacted Hantzsch amide and the bis-methylamidopyridine byproduct are effectively removed by extraction in contrast to the commonly used Hantzsch diethyl ester. Several examples are given with the reaction being more effective for conjugated aromatic substrates than for aliphatics.