3096-49-9Relevant articles and documents
Synthesis of highly substituted fluorenones via metal-free TBHP-promoted oxidative cyclization of 2-(aminomethyl)biphenyls. Application to the total synthesis of nobilone
Bracher, Franz,Jourjine, Ilya A. P.,Krau?, Jürgen,Zeisel, Lukas
supporting information, p. 2668 - 2679 (2021/11/30)
Highly substituted fluorenones are readily prepared in mostly fair to good yields via metal- and additive-free TBHP-promoted cross-dehydrogenative coupling (CDC) of readily accessible N-methyl-2-(aminomethyl)biphenyls and 2-(aminomethyl)biphenyls. This methodology is compatible with numerous functional groups (methoxy, cyano, nitro, chloro, and SEM and TBS-protective groups for phenols) and was further utilized in the first total synthesis of the natural product nobilone.
Spiroacridine-based compound, hole transport material containing said compound, and organic electronic device containing said compound in hole transport layer
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Paragraph 0127-0129, (2021/01/15)
The present invention addresses the problem of providing: a compound that can be used as a hole transport material having excellent hole injection or transport performance, electron blocking performance, light stability, electrical stability, and thermal stability; and a hole transport material containing the compound. Also provided is an organic electronic device including an organic EL device oran organic photoelectric conversion device having a hole transport layer containing the compound, and particularly provided is an organic electronic device including an organic EL device having a long lifetime and high luminous efficiency. The technical solution is to provide a compound represented by general formulae (1-1)-(1-3) (wherein n, L, R, and Ar1-Ar5 are as defined in the description) isprovided.
Amphiphilic ligands for Cu-catalyzed aerobic oxidation to synthesize 9-fluorenones in water
Li, Longjia,Liu, Zibo,Tang, Shanyu,Li, Jiao,Ren, Xuanhe,Yang, Guanyu,Li, Heng,Yuan, Bingxin
, p. 34 - 38 (2019/05/10)
A series of amphiphilic PEG-functionalized nitrogen ligands were developed for the highly efficient copper-catalyzed aerobic oxidation of 9-fluorenes, with molecular oxygen as the sole oxidant in neat water. A broad range of functional groups are well tolerated and thus offer the opportunity for further functionalization.