31067-15-9

Basic information

• Product Name: 1,1,4-triphenyl-1-butanol
• Synonyms: 1,1,4-triphenyl-1-butanol
• CAS NO: 31067-15-9
• Molecular Weight: 302.416
• Mol File: 31067-15-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,1,4-triphenyl-1-butanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,4-triphenyl-1-butanol(31067-15-9)
• EPA Substance Registry System: 1,1,4-triphenyl-1-butanol(31067-15-9)

Safety Data

• Hazardous Substances Data: 31067-15-9(Hazardous Substances Data)

Upstream product

• 119-61-9 benzophenone 
• 1462-75-5 3-phenylpropylmagnesium bromide 
• 10031-93-3 ethyl 4-phenylbutyrate 
• 6052-64-8 (E)-1,1,4-triphenyl-3-buten-1-ol 
• 591-51-5 phenyllithium 
• 1821-12-1 4-Phenylbutyric acid 
• 201230-82-2 carbon monoxide 
• 637-59-2 1-Bromo-3-phenylpropane 
• 54812-94-1 (3-phenylpropyl)magnesium chloride 
• 2046-17-5 methyl 3-(benzyl)propanoate 
• 100-58-3 phenylmagnesium bromide 
• 5449-47-8 4-methyl-1,1-diphenylpentan-1-ol 
• 55766-18-2 3-cyclohexyl-1,1-diphenylpropan-1-ol 
• 1454679-75-4 3-(adamantan-2-yl)-1,1-diphenylpropan-1-ol 

Downstream Products

• 38328-16-4 (1,4-diphenylbut-1-enyl)benzene 
• 111439-73-7 1,1-diphenyl-1,2,3,4-tetrahydronaphthalene 
• 91-01-0 1,1-Diphenylmethanol 
• 1454679-91-4 1,1,4-triphenylbutane-1,4-diol 
• 1454679-77-6 1,1,4-triphenylbutyl-1-hydroperoxide 
• 33885-05-1 2,2,5-triphenylpentanoicacid 

Relevant articles and documents

Iron-catalysed 1,2-aryl migration of tertiary azides

1,2-Aryl migration of α,α-diaryl tertiary azides was achieved by using the catalytic system of FeCl2/N-heterocyclic carbene (NHC) SIPr·HCl. The reaction generated aniline products in good yields after one-pot reduction of the migration-resultant imines.

Tetrahydronaphthalene derivatives by amberlyst 15-promoted friedel-crafts cyclizations

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One-pot synthesis of diarylalkylcarbinols and substituted derivatives through carbon monoxide insertion reactions into aryllithiums

The carbonylation of a THF solution of aryllithium (aryl = Ph, o-anisyl) in the presence of an alkyl bromide, RBr; at atmospheric pressure and -78 deg C, affords diarylalkylcarbinols in good yields.Alkyl chlorides do not react under similar experimental conditions.This feature makes the reaction particularly useful for the synthesisof alcohols functionalized in the alkyl chain through subsequent reactions of the diaryl(chloro)alkylcarbinols.The procedure can also be adapted to afford substituted cyclic ethers.If the reaction is carried out in the presence of dibromoalkanes, only one bromine atom reacts, affording diaryl(bromo)alkylcarbinols which are useful intermediates.With secondary and tertiary alkyl bromides diaryl alkyl ethers are obtained in variable yields.