31569-56-9

Basic information

• Product Name: Indium, tris(pentafluorophenyl)-
• CAS NO: 31569-56-9
• Molecular Formula: C18F15In
• Molecular Weight: 615.994
• Mol File: 31569-56-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Indium, tris(pentafluorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Indium, tris(pentafluorophenyl)-(31569-56-9)
• EPA Substance Registry System: Indium, tris(pentafluorophenyl)-(31569-56-9)

Safety Data

• Hazardous Substances Data: 31569-56-9(Hazardous Substances Data)

Upstream product

• 15989-98-7 bis(pentafluorophenyl)cadmium 
• 603-35-0 triphenylphosphine 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 10025-82-8 indium(III) chloride 
• 7440-74-6 indium 
• 973-17-1 bis(pentafluorophenyl)mercury(II) 
• 34422-57-6 tris(pentafluorophenyl)bismuth 
• 1735-62-2 Bromo-bis-(pentafluorphenyl)-thallium(III) 
• 827-15-6 1,2,3,4,5-pentafluoro-6-iodobenzene 
• 110-86-1 pyridine 
• 67-68-5 dimethyl sulfoxide 

Downstream Products

• 363-72-4 Pentafluorobenzene 

Relevant articles and documents

On the chemistry of fluoroorgano derivatives of group 13 elements. 2: Synthesis and characterization of the 1:1-adducts of In(C6F5)3 with acetonitrile, glyme, and DMAP (DMAP = 4-(N,N-dimethylamino)-pyridine), and [PNP][In(C6F5)4](PNP = bis(triphenylphosphinanyliden)-immonium)

In(C6F5)3 · CH3CN and In(C6F5)3 · glyme were synthesized from InCl3 and Cd(C6F5)2 in CH3CN or glyme in 43% and 35% yield, respectively. Replacement of CH3CN or (C2H5)2O by DMAP yielded the corresponding 1:1-adduct. [PNP][In(C6F5)4] was best prepared from the corresponding cesium salt which was best synthesized from the reaction of stoichiometric amounts of In(C6F5)3 · CH3CN, (CH3)3 SiC6F5 and CsF in good yield. _[PNP][In(C6F5)4] crystallizes in the triclinic space group P1, a = 1104.9(4) pm, b = 1442.4(6) pm, c = 1833.8(8) pm, α = 110.87(2)°, β = 92.04(3)°, γ = 96.55(3)°, Z = 2.