31889-28-8

Basic information

• Product Name: Pyrrolidine, 1-(1-phenyl-1-propenyl)-, (E)-
• CAS NO: 31889-28-8
• Molecular Formula: C13H17N
• Molecular Weight: 187.285
• Mol File: 31889-28-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Pyrrolidine, 1-(1-phenyl-1-propenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyrrolidine, 1-(1-phenyl-1-propenyl)-, (E)-(31889-28-8)
• EPA Substance Registry System: Pyrrolidine, 1-(1-phenyl-1-propenyl)-, (E)-(31889-28-8)

Safety Data

• Hazardous Substances Data: 31889-28-8(Hazardous Substances Data)

Upstream product

• 123-75-1 pyrrolidine 
• 93-55-0 1-phenyl-propan-1-one 

Downstream Products

• 1846-29-3 1,3-diphenyl-2-methylpropane-1,3-dione 
• 1064675-92-8 1-(1-phenyl-1-trifluoromethylprop-1-yl)pyrrolidine 
• 89649-53-6 4-methyl-3,5-diphenylpyrrole-2-carboxylate de methyle 
• 253609-30-2 (1'R,2R,3S,5'R)-3-(2'-azabicyclo[3.3.0]octane-2'-yl)-2-methylpropanone 
• 96898-18-9 ethyl 4-methyl-3-phenylpyridine-2-carboxylate 
• 10488-96-7 5-Methyl-2,6-diphenylpyrimidin-4(3H)-one 
• 89649-22-9 3'-Methyl-2',4'-diphenyl-2,3,4,5,2',3'-hexahydro-1'H-[1,2']bipyrrolyl-5'-carboxylic acid methyl ester 
• 124887-92-9 anti-2,2-dimethoxy-3,4-dimethyl-5-oxo-5-phenylpentanoate 

Relevant articles and documents

Tf2O-Mediated Intermolecular Coupling of Secondary Amides with Enamines or Ketones: A Versatile and Direct Access to β-Enaminones

Based on the Tf2O-mediated intermolecular reaction of secondary amides with enamines derived from ketones, a novel approach to β-enaminones has been developed. The reaction is widely functional group tolerant and highly chemoselective. In the presence of 4 ? molecular sieves, the method can be extended to the one-pot condensation of secondary amides with ketones for NH β-enaminones synthesis.

178. Stereoselectivity of the Radical Reductive Alkylation of Enamines: Importance of the Allylic 1,3-Strain Model

Radical addition to enamines using Bu3SnH as reducing agent are reported (Schemes 2 and 4).The diastereoselectivity of these reactions was examined in different systems (Tables 1 and 2).Enamines derived from cyclic ketones such as cyclohexanone were alkyl