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3225-26-1

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3225-26-1 Usage

Description

4-BENZOYLOXY-TEMPO, also known as 4-Hydroxy-TEMPO benzoate, is a 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivative. It is an orange crystalline powder that serves as a recycling catalyst in various chemical reactions.

Uses

Used in Chemical Synthesis:
4-BENZOYLOXY-TEMPO is used as a recycling catalyst in the hypochlorite/bromite-nitroxide oxidizing system for the conversion of alcohols to aldehydes, ketones, and carboxylic acids. It is particularly useful as it eliminates the need to use a catalytic or stoichiometric heavy metal oxidant, which can be harmful to the environment and human health.
Used in Environmental Applications:
In the environmental industry, 4-BENZOYLOXY-TEMPO is used as a catalyst to facilitate the oxidation of pollutants, thus aiding in the detoxification and clean-up processes. Its ability to replace heavy metal oxidants makes it a more sustainable and safer option for environmental applications.
Used in Pharmaceutical Industry:
4-BENZOYLOXY-TEMPO can be utilized in the pharmaceutical industry as a catalyst for the synthesis of various drugs and drug intermediates. Its efficiency in catalyzing the conversion of alcohols to other functional groups can streamline the drug synthesis process and potentially reduce the production of harmful by-products.
Used in Material Science:
In the field of material science, 4-BENZOYLOXY-TEMPO can be employed as a catalyst for the synthesis of advanced materials, such as polymers and composites, with specific properties. Its ability to catalyze the conversion of alcohols to other functional groups can be crucial in tailoring the material's characteristics for various applications.

Check Digit Verification of cas no

The CAS Registry Mumber 3225-26-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,2,2 and 5 respectively; the second part has 2 digits, 2 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 3225-26:
(6*3)+(5*2)+(4*2)+(3*5)+(2*2)+(1*6)=61
61 % 10 = 1
So 3225-26-1 is a valid CAS Registry Number.
InChI:InChI=1/C16H22NO3/c1-15(2)10-13(11-16(3,4)17(15)19)20-14(18)12-8-6-5-7-9-12/h5-9,13H,10-11H2,1-4H3

3225-26-1 Well-known Company Product Price

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  • TCI America

  • (H0878)  4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Benzoate Free Radical [Catalyst for Oxidation]  >97.0%(GC)

  • 3225-26-1

  • 1g

  • 660.00CNY

  • Detail
  • TCI America

  • (H0878)  4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Benzoate Free Radical [Catalyst for Oxidation]  >97.0%(GC)

  • 3225-26-1

  • 5g

  • 1,990.00CNY

  • Detail
  • Aldrich

  • (371343)  4-Hydroxy-TEMPObenzoate,freeradical  97%

  • 3225-26-1

  • 371343-1G

  • 723.06CNY

  • Detail

3225-26-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name (1-λ<sup>1</sup>-oxidanyl-2,2,6,6-tetramethylpiperidin-4-yl) benzoate

1.2 Other means of identification

Product number -
Other names 4-benzoyloxy-2,6-tetramethylpiperidine-N-oxyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3225-26-1 SDS

3225-26-1Relevant articles and documents

Full Organic Aqueous Battery Based on TEMPO Small Molecule with Millimeter-Thick Electrodes

Perticarari, Sofia,Grange, Elodie,Doizy, Tom,Pellegrin, Yann,Quarez, Eric,Oyaizu, Kenichi,Fernandez-Ropero, Antonio Jesus,Guyomard, Dominique,Poizot, Philippe,Odobel, Fabrice,Gaubicher, Jo?l

, p. 1869 - 1880 (2019)

Thick electrodes with sodium and even anion intercalation organic compounds integrated in a neutral-pH aqueous battery offer unique advantages in terms of round trip efficiency, environmental impact, and scalability for off- or on-grid renewable energy st

METHOD OF PRODUCING N-OXYL COMPOUND

-

Paragraph 0063; 0064, (2016/12/16)

PROBLEM TO BE SOLVED: To provide a safe and convenient method of producing an N-oxyl compound without using a special reaction device. SOLUTION: A compound represented by a following formula is obtained by the reaction between 4-hydroxy-2,2,6,6-tetramethylpiperidine 1-oxyl and aromatic acid chloride in the presence of tertiary amine (where at least one of R1 and R2 is a group represented by a following formula). COPYRIGHT: (C)2016,JPOandINPIT

Inhibiting polymerization of vinyl aromatic monomers

-

, (2008/06/13)

When a nitroxyl compound is heated in an oxygen-free atmosphere with a vinyl aromatic monomer at 50-140 DEG C. for up to 60 days, it forms an activated inhibitor mixture which is superior to the nitroxyl compound itself in preventing the premature polymerization of a vinyl aromatic monomer during its processing and purification.

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