3237-31-8

Basic information

• Product Name: NSC30185
• Synonyms: NSC30185
• CAS NO: 3237-31-8
• Molecular Formula: C₁₂H₁₇NO₂S
• Molecular Weight: 239.33388
• Mol File: 3237-31-8.mol
• Article Data: 28

Chemical Properties

• Boiling Point: 374.7°Cat760mmHg
• Flash Point: 180.4°C
• Appearance: /
• Density: 1.2g/cm³
• Vapor Pressure: 8.22E-06mmHg at 25°C
• Refractive Index: 1.569
• CAS DataBase Reference: NSC30185(CAS DataBase Reference)
• NIST Chemistry Reference: NSC30185(3237-31-8)
• EPA Substance Registry System: NSC30185(3237-31-8)

Safety Data

• Hazardous Substances Data: 3237-31-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H17NO2S/c14-16(15,12-9-5-2-6-10-12)13-11-7-3-1-4-8-11/h2,5-6,9-11,13H,1,3-4,7-8H2

Upstream product

• 108-91-8 cyclohexylamine 
• 98-10-2 benzenesulfonamide 
• 110-83-8 cyclohexene 
• 603-33-8 triphenylbismuthane 
• 1122-60-7 1-nitrocyclohexane 
• 108-98-5 thiophenol 
• 80-17-1 benzenesufonyl hydrazide 
• 110-82-7 cyclohexane 
• 98-11-3 benzenesulfonic acid 
• 873-55-2 sodium benzenesulfonate 
• 108-94-1 cyclohexanone 
• 98-09-9 benzenesulfonyl chloride 
• 54769-59-4 N-hydroxybenzotriazole ester of benzenesulfonic acid 
• 35810-04-9 benzenesulfinic acid cyclohexylamide 

Downstream Products

• 1620220-80-5 C₁₆H₂₁NO₃S 
• 1620220-90-7 1-cyclohexyl-3-methyl-3-(tosylmethyl)indolin-2-one 
• 200408-41-9 2,2'-diselenobis(N-cyclohexyl benzenesulfonamide) 
• 41595-23-7 N-Cyclohexyl-N-(benzolsulfenyl)benzolsulfonamid 
• 15963-66-3 N-Chlor-N-benzolsulfonyl-cyclohexylamin 
• 65299-65-2 N-Cyclohexyl-N,N-di(benzol)sulfonimid 

Relevant articles and documents

Phosphine/Photoredox Catalyzed Anti-Markovnikov Hydroamination of Olefins with Primary Sulfonamides via α-Scission from Phosphoranyl Radicals

New strategies to access radicals from common feedstock chemicals hold the potential to broadly impact synthetic chemistry. We report a dual phosphine and photoredox catalytic system that enables direct formation of sulfonamidyl radicals from primary sulf

A Versatile Electrochemical Batch Reactor for Synthetic Organic and Inorganic Transformations and Analytical Electrochemistry

A standardized and versatile electrochemical batch reactor that has wide applicability in both organic and inorganic synthesis and analytical electrochemistry has been developed. A variety of synthetic electrochemical transformations have been performed to showcase the versatility and demonstrate the reactor, including the synthesis of five Cu(I)-NHC complexes, two Au(I)-NHC complexes, and one Fe(II)-NHC complex as well as an Fe(III)-salen complex. The reactor is based on a commercially available vial with an adapted lid, making it inexpensive and highly flexible. It features a fixed interelectrode distance, which is crucial for reproducibility, along with the ability to accommodate a variety of interchangeable electrode materials. The reactor has also been used in conjunction with a parallel plate, allowing rapid screening and optimization of an organic electrochemical transformation. Cyclic voltammetry has been performed within the reactor on a range of imidazolium salt analytes with the use of an external potentiostat. The ability to use this reactor for both analytical and synthetic organic and inorganic chemistry is enabled by a flexible and characterizable design.

Iron-Catalyzed Hydroamination and Hydroetherification of Unactivated Alkenes

The hydrofunctionalization of alkenes, explored for over 100 years, offers the potential for a direct, atom-economical approach to value-added products. While thermodynamically favored, the kinetic barrier to such processes necessitates the use of catalysts to control selectivity and reactivity. Modern variants typically rely on noble metals that require different ligands for each class of hydrofunctionalization, thereby limiting generality. This Letter describes a general iron-based system that catalyzes the hydroamination and hydroetherification of simple unactivated olefins.