32569-84-9

Basic information

• Product Name: Benzene, (ethoxyethynyl)-
• CAS NO: 32569-84-9
• Molecular Formula: C10H10O
• Molecular Weight: 146.189
• Mol File: 32569-84-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, (ethoxyethynyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (ethoxyethynyl)-(32569-84-9)
• EPA Substance Registry System: Benzene, (ethoxyethynyl)-(32569-84-9)

Safety Data

• Hazardous Substances Data: 32569-84-9(Hazardous Substances Data)

Upstream product

• 13049-42-8 phenylketene diethylacetal 
• 71-43-2 benzene 
• 536-74-3 phenylacetylene 
• 1483-82-5 phenylethynyl chloride 
• 141-52-6 sodium ethanolate 
• 24648-07-5 2-Phenyl-1,3,3-trichlorocyclopropene 
• 67500-35-0 1-ethoxy-2-iodoacetylene 
• 591-50-4 iodobenzene 
• 137344-20-8 ethoxy(tributylstannyl)acetylene 
• 23268-50-0 Ethyl(trimethylstannylethinyl)ether 
• 156336-58-2 2-Ethoxy-3-phenylcyclopropenone 
• 42345-82-4 (E)-1,2-dichloro-1-ethoxy-ethene 
• 640-60-8 toluene-4-sulfonic acid phenyl ester 
• 36678-63-4 ethoxyethynylmagnesium bromide 

Downstream Products

• 19307-81-4 β,β-Dichlor-α-phenyl-acrolein-semicarbazon 
• 36586-15-9 (2-ethoxyethene-1,1-diyl)dibenzene 
• 947-91-1 Diphenylacetaldehyde 
• 50600-30-1 2-(4-methylphenyl)-2-(phenyl)acetaldehyde 
• 28523-15-1 2-(4-chlorophenyl)-2-phenylacetaldehyde 
• 83463-80-3 3-ethoxy-2-phenylquinoline 

Relevant articles and documents

Manganese-Catalyzed Dual-Deoxygenative Coupling of Primary Alcohols with 2-Arylethanols

Reported herein is a general and efficient dual-deoxygenative coupling of primary alcohols with 2-arylethanols catalyzed by a well-defined Mn/PNP pincer complex. This reaction is the first example of the catalytic dual-deoxygenation of alcohols using a non-noble-metal catalyst. Both deoxygenative homocoupling of 2-arylethanols (17 examples) and their deoxygenative cross-coupling with other primary alcohols (20 examples) proceeded smoothly to form the corresponding alkenes by a dehydrogenation and deformylation reaction sequence.

Ynol Ethers as Ketene Equivalents in Rhodium-Catalyzed Intermolecular [5 + 2] Cycloaddition Reactions

The previously unexplored metal-catalyzed [5 + 2] cycloadditions of vinylcyclopropanes (VCPs) and electron-rich alkynes (ynol ethers) have been found to provide a highly efficient, direct route to dioxygenated seven-membered rings, a common feature of num

Convenient and General Synthesis of 2-Alkoxy-3-arylcyclopropenones

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