36586-15-9

Basic information

• Product Name: Benzene, 1,1'-(ethoxyethenylidene)bis-
• CAS NO: 36586-15-9
• Molecular Formula: C16H16O
• Molecular Weight: 224.302
• Mol File: 36586-15-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(ethoxyethenylidene)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(ethoxyethenylidene)bis-(36586-15-9)
• EPA Substance Registry System: Benzene, 1,1'-(ethoxyethenylidene)bis-(36586-15-9)

Safety Data

• Hazardous Substances Data: 36586-15-9(Hazardous Substances Data)

Upstream product

• 530-48-3 1,1-Diphenylethylene 
• 64-17-5 ethanol 
• 591-50-4 iodobenzene 
• 32569-84-9 ethoxyethynylbenzene 
• 337-72-4 2-fluoro-1,1-diphenylethan-1-ol 
• 7647-01-0 hydrogenchloride 
• 64-19-7 acetic acid 
• 135-19-3 β-naphthol 
• 53377-98-3 3-ethoxy-2,2-diphenylthietane 
• 390-75-0 2-fluoro-1,1-diphenylethene 
• 4541-89-3 2-chloro-1,1-diphenylethene 
• 141-52-6 sodium ethanolate 

Downstream Products

• 861010-02-8 1,1-bis-(4-hydroxy-phenyl)-2,2-diphenyl-ethane 
• 947-91-1 Diphenylacetaldehyde 
• 75-00-3 chloroethane 
• 806-58-6 1,2,4-triphenylnaphthalene 

Relevant articles and documents

Photocatalytic Dehydrogenative Cross-Coupling of Alkenes with Alcohols or Azoles without External Oxidant

Direct cross-coupling between alkenes/R-H or alkenes/RXH is a dream reaction, especially without external oxidants. Inputting energy by photocatalysis and employing a cobalt catalyst as a two-electron acceptor, a direct C?H/X?H cross-coupling with H2evolution has been achieved for C?O and C?N bond formation. A new radical alkenylation using alkene as the redox compound is presented. A wide range of aliphatic alcohols—even long chain alcohols—are tolerated well in this system, providing a new route to multi-substituted enol ether derivatives using simple alkenes. Additionally, this protocol can also be used for N-vinylazole synthesis. Mechanistic insights reveal that the cobalt catalyst oxidizes the photocatalyst to revive the photocatalytic cycle.

Ring-Splitting of 2,2-Diarylthiethane by Electron-Transfer Photosensitization of 9,10-Dicyanoanthracene

A 9,10-dicyanoanthracene (DCA)-photosensitized reaction of 3-cyano- or 3-ethoxy-2,2-diarylthietane in acetonitrile gave selectively 2-cyano- or 2-ethoxy-1,1-diarylethene.The ring-splitting reaction proceeds via a one-electron oxidation of the sulfur atom of thietane ring by a photochemical electron transfer to the excited singlet state of DCA.