329009-01-0Relevant articles and documents
Thermal decomposition of 4-fluorobenzenediazonium perfluoroorganyl(fluoro) borates, [4-FC6H4N2]Y (Y = RFBF 3 (RF = C6F5, C6F 13, trans-C4F9CFCF, cis-C6F 13CFCF, CF3CC) and (C6F13) 2BF2)
Bardin, Vadim V.,Frohn, Hermann-Josef
, p. 333 - 338 (2014/01/06)
Heating of the neat salts [4-FC6H4N 2][RFBF3] (RF = C6F 5, C6F13, trans-C4F9CFCF, cis-C6F13CFCF, CF3CC) or in solid mixtures with NaF gives the principal product 1,4-C6F2H4 besides RFBF2 or Na[RFBF3], respectively. Thermolysis of [4-FC6H4N2] [(C6F13)2BF2] in NaF results in 1,4-C6F2H4, Na[BF4], Na[(C 6F13)2BF2], and a new type of product, the isomer Na[C6F13CF(BF3)C 5F11].