33143-51-0

Basic information

• Product Name: (E)-N-(3-phenylallyl)carbamic acid methyl ester
• Synonyms: (E)-N-(3-phenylallyl)carbamic acid methyl ester
• CAS NO: 33143-51-0
• Molecular Weight: 191.23
• Mol File: 33143-51-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (E)-N-(3-phenylallyl)carbamic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-N-(3-phenylallyl)carbamic acid methyl ester(33143-51-0)
• EPA Substance Registry System: (E)-N-(3-phenylallyl)carbamic acid methyl ester(33143-51-0)

Safety Data

• Hazardous Substances Data: 33143-51-0(Hazardous Substances Data)

Upstream product

• 104-55-2 3-phenyl-propenal 
• 598-55-0 methyl carbamate 
• 21040-45-9 Cinnamyl acetate 
• 1189-71-5 isocyanate de chlorosulfonyle 
• 16277-67-1 (Z)-(3-methoxyprop-1-en-1-yl)benzene 
• 24808-73-9 (E)-(3-methoxyprop-1-en-1-yl)benzene 
• 22665-13-0 1-phenylallyl methyl ether 

Downstream Products

• 4335-60-8 (E)-cinnamylamine 

Relevant articles and documents

Rapid and convenient microwave-assisted synthesis of primary amines via reductive N-alkylation of methyl carbamate with aldehydes

Microwave-assisted reductive alkylation of methyl carbamate with a range of aldehydes provides, after basic work-up, an experimentally simple, one-pot method for rapid functional group interconversion of structurally diverse aldehydes into primary amines. The method has several advantages over more traditional methods of carrying out this transformation and is particularly amenable to high-throughput synthesis.

Synthesis of N-protected allylic amines from allyl ethers

A synthetic method for N-protected allylic amines from allyl ethers using chlorosulfonyl isocyanate (CSI) is presented. The reaction of 4-phenylbut-2-enyl methyl ether (1i) with CSI afforded methyl N-(1-benzylallyl)carbamate (2i) and methyl N-(4-phenylbut

Palladium(0)-Catalyzed Amination of Allylic Acetate with Methyl Carbamate

Methyl sodiocarbamate, a recalcitrant nucleophile toward ?-allylpalladium intermediate, was found to react with allylic acetates to give allylic carbamates in the presence of a catalytic amount of Pd(PPh3)4 in THF-DMSO mixed solvent.