331626-90-5

Basic information

• Product Name: methyl 2-(2-methoxy-4-methylphenyl)propanethiolate
• Synonyms: methyl 2-(2-methoxy-4-methylphenyl)propanethiolate
• CAS NO: 331626-90-5
• Molecular Weight: 224.324
• Mol File: 331626-90-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2-(2-methoxy-4-methylphenyl)propanethiolate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(2-methoxy-4-methylphenyl)propanethiolate(331626-90-5)
• EPA Substance Registry System: methyl 2-(2-methoxy-4-methylphenyl)propanethiolate(331626-90-5)

Safety Data

• Hazardous Substances Data: 331626-90-5(Hazardous Substances Data)

Upstream product

• 221354-43-4 2-<4-methyl-2-(methoxy)phenyl>-1-tetrahydro-2H-1,4-oxazin-4-yl-1-ethanthione 
• 35633-35-3 2-methoxy-4-methylacetophenone 
• 122-46-3 3-acetoxytoluene 
• 6921-64-8 4'-hydroxy-2'-methylacetophenone 

Downstream Products

• 64052-99-9 rel-(3S,3aS,8bS)-7-bromo-3,6,8b-trimethyl-2,3,3a,8b-tetrahydro-1H-benzo[b]cyclopenta[d]furan-3a-carbaldehyde 
• 65817-24-5 3,6-dimethyl-3H-benzo[b]furan-2-one 

Relevant articles and documents

The synthesis of a natural product family: From debromoisolaurinterol to the aplysins

Total syntheses of (±)-aplysin 1, (±)-debromoaplysin 2, (±)-isoaplysin 3, (±)-aplysinol 4, (±)-debromoaplysinol 5, (±)-aplysinal 6, (±)-isolaurinterol 7 and (±)-debromoisolaurinterol 8 are described. Key features are a diastereoselective, sulfur mediated radical cyclisation of diene 12 to give 35; a new radical to polar crossover sequence mediated by Bu3Sn that transforms diene 12 into (±)-debromoisolaurinterol 8; and a series of biomimetic cyclisation and oxidation reactions.