335-10-4Relevant articles and documents
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Johncock,P.
, p. 257 - 265 (1969)
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A novel and efficient synthetic route to perfluoroisobutyronitrile from perfluoroisobutyryl acid
Wang, Yi,Sun, Mengting,Gao, Zhanyang,Zou, Lilin,Zhong, Lingyu,Peng, Ruichao,Yu, Ping,Luo, Yunbai
, p. 37159 - 37164 (2018/11/26)
A novel synthetic route to perfluoroisobutyronitrile from perfluoroisobutyryl acid which has mild conditions and low toxicity is described. This study introduces detailed synthetic protocols and characterization including GC-MS, 13C NMR and 19F NMR spectroscopy of perfluoroisobutyryl acid, perfluoroisobutyryl chloride, perfluoroisobutyl amide and perfluoroisobutyronitrile. Besides, this route is superior to the established patent and shows potential application in high voltage electrical equipment.
Free-radical selective functionalization of 1,4-naphthoquinones by perfluorodiacyl peroxides
Sansotera, Maurizio,Gambarotti, Cristian,Famulari, Antonino,Baggioli, Alberto,Soave, Raffaella,Venturini, Francesco,Meille, Stefano V.,Wlassics, Ivan,Navarrini, Walter
, p. 5298 - 5309 (2014/07/08)
Perfluoroalkyl radicals, generated by thermal decomposition of perfluorodiacyl peroxides, react selectively with quinone rings of 1,4-naphthoquinones. In the presence of a non-conjugated alkene such as 1-hexene, perfluoroalkyl radicals add to the double bonds of the olefin forming a radical adduct, which selectively adds to the naphthoquinone ring. Several perfluorodiacyl peroxides have been synthesized and used for the direct and alkene-mediated functionalization of naphthoquinones. Geometrical parameters and electron density topology of all perfluorodiacyl peroxides have been calculated by the density functional formalism and quantum theory of atoms in molecules to attempt a rationalization of the experimental reactivity.