3360-52-9

Basic information

• Product Name: Benzene, [1-(chloromethyl)ethenyl]-
• Synonyms: 1-chloro-2-phenyl-2-propene;2-phenylacrylyl chloride
• CAS NO: 3360-52-9
• Molecular Formula: C9H9Cl
• Molecular Weight: 152.623
• Mol File: 3360-52-9.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 88-89 °C
• Density: 1.040±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzene, [1-(chloromethyl)ethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [1-(chloromethyl)ethenyl]-(3360-52-9)
• EPA Substance Registry System: Benzene, [1-(chloromethyl)ethenyl]-(3360-52-9)

Safety Data

• Hazardous Substances Data: 3360-52-9(Hazardous Substances Data)

Upstream product

• 98-82-8 Isopropylbenzene 
• 14596-60-2 N-chloro-N-(4-methylphenyl)acetamide 
• 5155-87-3 3-phenylbut-3-enoic acid 
• 127-65-1 chloroamine-T 
• 98-83-9 isopropenylbenzene 
• 7534-40-9 2-phenylallyl acetate 
• 3360-54-1 3-bromo-2-phenylprop-1-ene 
• 67300-99-6 1-phenylethenylmagnesium bromide 
• 701285-61-2 C₁₀H₉ClO 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 532-27-4 1-chloroacetophenone 
• 6006-81-1 3-hydroxy-2-phenylpropene 

Downstream Products

• 58463-02-8 (1E,5E)-1,6-diphenyl-1,5-hexadiene 
• 4743-73-1 2-methyl-3-phenylpent-4-en-2-ol 
• 4403-14-9 3,4-diphenylhexa-1,5-diene 
• 74120-63-1 (E)-1,4-diphenyl-1,5-hexadiene 
• 84538-94-3 1-benzylthio-2-phenyl-2-propene 
• 74866-37-8 [3-(benzenesulfonyl)prop-1-en-2-yl]benzene 
• 127158-86-5 1-cyclopropylsulphonyl-2-phenyl-2-propene 
• 1613753-06-2 diphenyl(2-phenylallyl)phosphine 
• 7283-49-0 2,5-diphenyl-hexa-1,5-diene 
• 57132-29-3 4-hydroxy-2-phenyl-1-pentene 
• 98-83-9 isopropenylbenzene 
• 5155-87-3 3-phenylbut-3-enoic acid 
• 64011-01-4 2-((2-phenylallyl)oxy)ethanol 
• 25957-50-0 N-acetylamino-3 phenyl-2 propene 

Relevant articles and documents

One-Pot Twofold Unsymmetrical C-Si Bond 2,6-Bifunctionalization of Arenes via Sequential [1,4]-Csp2 to O-Silyl Migration

Twofold unsymmetrical C-Si bond bifunctionalization of 2,6-di(trimethylsilyl) benzyl alcohols has been achieved in one pot via sequential [1,4]-Csp2 to O-silyl migration. The hydroxyl group functions as an "on-off-on" switch to control two successive silyl migrations, and 4,7-dimethyl-o-phenanthroline ligand favors cleavage of the endocyclic C-Si bond. Diverse Csp3/Csp3 or Csp2/Csp3 electrophiles can be installed at the 2- and 6-positions. This approach was used to chemoselectively functionalize the three C-Si bonds of 2,4,6-tri(trimethylsilyl) benzyl alcohol, transforming it into isochroman derivatives. The approach even works as a five-component reaction to construct complex symmetric structures.

A mild and efficient method for the synthesis of a new optically active diallyl selenide and its catalytic activity in the allylic chlorination of natural terpenes

A mild and convenient method for the synthesis of a new optically active bis(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-ylmethyl)selenide 1 from the corresponding bicyclic terpene is described. The structure of the obtained organoselenium compound was establis

Halofluorination of alkenes using trihaloisocyanuric acids and HF-pyridine

Halofluorination of alkenes with a new system (trihaloisocyanuric acids and HF-pyridine) results in the formation of vicinal halofluoroalkanes. The reaction is regioselective leading to Markovnikov-oriented products and the halofluorinated adducts follow anti-addition in the case of cyclohexene and 1-methylcyclohexene. Reaction yields range from 67-88%. Georg Thieme Verlag Stuttgart · New York.