33813-99-9

Basic information

• Product Name: Grundmann's alcohol
• Synonyms: Grundmann's alcohol
• CAS NO: 33813-99-9
• Molecular Weight: 266.467
• Mol File: 33813-99-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Grundmann's alcohol(CAS DataBase Reference)
• NIST Chemistry Reference: Grundmann's alcohol(33813-99-9)
• EPA Substance Registry System: Grundmann's alcohol(33813-99-9)

Safety Data

• Hazardous Substances Data: 33813-99-9(Hazardous Substances Data)

Upstream product

• 84927-67-3 3β-O-(tert-butyldimethylsilyl)-7,8-dihydroxy-7,8-dihydrovitamin D3 

Downstream Products

• 32222-06-3 calcitriol 
• 873567-12-5 (1R,3aS,7aR)-1-((R)-5-Methoxymethoxy-1,5-dimethyl-hexyl)-7a-methyl-4-[2-[(3S,5R)-2-methylene-3,5-bis-triisopropylsilanyloxy-cyclohex-(Z)-ylidene]-eth-(E)-ylidene]-octahydro-indene 
• 70550-73-1 (1R,3aR,7aR)-1-[(2R)-6-hydroxy-6-methylhept-2-yl]-7a-methyloctahydroinden-4-one 
• 66251-18-1 Grundmann's ketone 
• 75197-02-3 (1R,3aS,7aR)-1-[(R)-1,5-dimethylhexyl]-7a-methyloctahydroinden-4-one 
• 119569-20-9 (3aR)-1t-((R)-1,5-dimethyl-hexyl)-4t-(3,5-dinitro-benzoyloxy)-7a-methyl-(3ar,7at)-hexahydro-indan 
• 138924-23-9 (3R,3aR,7aR)-7-{(Z)-2-[(3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2-methyl-cyclohex-1-enyl]-vinyl}-3-((R)-1,5-dimethyl-hexyl)-3a-methyl-2,3,3a,4,5,7a-hexahydro-1H-indene 
• 138924-22-8 (1R,3aS,7aR)-4-[2-[(3S,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2-methylene-cyclohex-(Z)-ylidene]-eth-(E)-ylidene]-1-((R)-1,5-dimethyl-hexyl)-7a-methyl-octahydro-indene 
• 41294-56-8 1α-hydroxyvitamin D3 
• 96685-51-7 (-)-<1R,2'R,5R,6R,9R>-1-methyl-9-(6-methylhept-2-yl)-5-(phenylsulfonyl)bicyclo<4.3.0>-3-nonene 
• 96685-52-8 (+)-<1R,2'R,5R,6R,9R>-1-methyl-9-(6-methylhept-2-yl)-5-(phenylsulfonyl)bicyclo<4.3.0>nonane 
• 178765-12-3 (1R,3aR,7aR)-4-[2-[(3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methylene-cyclohex-(Z)-ylidene]-eth-(E)-ylidene]-1-((R)-1,5-dimethyl-5-triethylsilanyloxy-hexyl)-octahydro-indene 
• 755002-31-4 Phosphoric acid dibenzyl ester (1R,3aR,4S,7aR)-1-((R)-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-4-yl ester 
• 66774-84-3 de-A,B-25-hydroxycholestan-8β-ol 

Relevant articles and documents

Studies on a Convergent Route to Side-Chain Analogues of Vitamin D: 25-Hydroxy-23-oxavitamin D3

Permanganate oxidation of vitamin D3 affords the 7,8-diol 4a, which was successively silylated to 4b and then oxidatively cleaved and reduced to afford 3c.The latter was converted in several steps to phosphine oxide 3b, a useful A-ring fragment for analog