33967-18-9

Basic information

• Product Name: Benzenemethanol, 4-ethyl-a-methyl-
• CAS NO: 33967-18-9
• Molecular Formula: C10H14O
• Molecular Weight: 150.221
• Mol File: 33967-18-9.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 4-ethyl-a-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 4-ethyl-a-methyl-(33967-18-9)
• EPA Substance Registry System: Benzenemethanol, 4-ethyl-a-methyl-(33967-18-9)

Safety Data

• Hazardous Substances Data: 33967-18-9(Hazardous Substances Data)

Upstream product

• 937-30-4 4-ethylacetophenone 
• 13372-42-4 1-Ethyl-4-<1-chlor-ethyl>-benzol 
• 105-05-5 1,4-diethylbenzene 
• 1566593-65-4 C₁₆H₂₅BO₃ 
• 100-41-4 ethylbenzene 
• 64-17-5 ethanol 
• 40307-11-7 1-ethyl-4-ethynylbenzene 

Downstream Products

• 33533-54-9 1-(4-ethylphenyl)ethyl hydrogen phthalate 
• 101219-72-1 (S)-1-(4-ethylphenyl)ethan-1-ol 
• 54225-75-1 1-(R)-(4'-ethylphenyl)ethanol 
• 103966-60-5 1-(α-acetoxyethyl)-4-ethylbenzene 
• 13372-42-4 1-Ethyl-4-<1-chlor-ethyl>-benzol 
• 59770-97-7 1-Brom-1-(p-ethylphenyl)-ethan 
• 103966-60-5 (S)-1-(4-ethylphenyl)ethyl acetate 
• 103966-60-5 (R)-1-(4-ethylphenyl)ethyl acetate 
• 937-30-4 4-ethylacetophenone 
• 4748-78-1 4-ethylbenzylaldehyde 
• 10537-63-0 1-(4-vinylphenyl)ethanone 
• 108673-17-2 rac-1-(4-(1-hydroxyethyl)phenyl)ethan-1-one 
• 125246-99-3 phthalic acid mono-[(R)-1-(4-ethyl-phenyl)-ethyl ester] 
• 473700-72-0 phthalic acid mono-[(S)-1-(4-ethyl-phenyl)-ethyl ester] 

Relevant articles and documents

Selective Carbon-Carbon Bond Amination with Redox-Active Aminating Reagents: A Direct Approach to Anilines?

Amines are among the most fundamental motifs in chemical synthesis, and the introduction of amine building blocks via selective C—C bond cleavage allows the construction of nitrogen compounds from simple hydrocarbons through direct skeleton modification. Herein, we report a novel method for the preparation of anilines from alkylarenes via Schmidt-type rearrangement using redox-active amination reagents, which are easily prepared from hydroxylamine. Primary amines and secondary amines were prepared from corresponding alkylarenes or benzyl alcohols under mild conditions. Good compatibility and valuable applications of the transformation were also displayed.

Transfer Hydrogenation of Ketones and Imines with Methanol under Base-Free Conditions Catalyzed by an Anionic Metal-Ligand Bifunctional Iridium Catalyst

An anionic iridium complex [Cp*Ir(2,2′-bpyO)(OH)][Na] was found to be a general and highly efficient catalyst for transfer hydrogenation of ketones and imines with methanol under base-free conditions. Readily reducible or labile substituents, such as nitro, cyano, and ester groups, were tolerated under present reaction conditions. Notably, this study exhibits the unique potential of anionic metal-ligand bifunctional iridium catalysts for transfer hydrogenation with methanol as a hydrogen source.

Method for synthesizing secondary alcohol

The invention discloses a method for synthesizing secondary alcohol, which utilizes transition metal catalysis and uses isopropanol as a hydrogen source to synthesize the secondary alcohol. The reaction not only uses inexpensive and environmentally friendly isopropanol as the hydrogen source and a solvent, but also has the advantages of high yield, environmental protection, and the like, and therefore the reaction has broad development prospects.