34557-72-7

Basic information

• Product Name: 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride
• CAS NO: 34557-72-7
• Molecular Weight: 703.124
• Mol File: 34557-72-7.mol
• Article Data: 37

Chemical Properties

• CAS DataBase Reference: 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride(34557-72-7)
• EPA Substance Registry System: 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride(34557-72-7)

Safety Data

• Hazardous Substances Data: 34557-72-7(Hazardous Substances Data)

Upstream product

• 56413-47-9 azidomanganese(III) meso-tetraphenylporphyrin 
• 90-13-1 1-Chloronaphthalene 
• 917-23-7 5,10,15,20-tetraphenyl-21H,23H-porphine 
• 85185-72-4 [ClMn(meso-tetraphenylporphinato)(OIPh)]2O 
• 58356-65-3 manganese(III) meso-tetraphenylporphyrin acetate 
• 85135-24-6 manganese(III)OH tetraphenylporphyrin 
• 14977-07-2 5,10,15,20-tetraphenylporphyrinato cadmium(II) 
• 7773-01-5 manganese(ll) chloride 
• 638-38-0 manganese(II) acetate 
• 7647-14-5 sodium chloride 
• 917-23-7 5,15,10,20-tetraphenylporphyrin 
• 67161-73-3 Mn(TPP)(ClO₄) 
• 89789-33-3 tetraphenylporphinatomanganese(III) fluoride 
• 58356-65-3 [MnIII(TPP)(OAc)] 

Downstream Products

• 143-07-7 lauric acid 
• 76077-77-5 ClMn(IV)(O)(tetraphenylporphyrin) 
• 31004-82-7 manganese(II) 5,10,15,20-tetraphenylporphyrinate 
• 71155-87-8 manganese(III)tetraphenylporphine(pyridine)⁽¹⁺⁾ 
• 83632-54-6 nitridomanganese(V) meso-tetraphenylporphyrinate 
• 58356-65-3 manganese(III) meso-tetraphenylporphyrin acetate 
• 55290-32-9 bromo(5,10,15,20-tetraphenylporphyrinato)manganese(III) 
• 105121-85-5 Mn(C₆H₅C₅H₂N)4(CF₃SO₃) 
• 83160-29-6 (dimethylsulfato-κO)(5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-κN(21),κN(22),κN(23),κN(24))manganese(II) 
• 57034-31-8 manganese(II)tetraphenylporphine(pyridine) 
• 54438-78-7 (tetraphenylporphyrin)(nitrosyl)MnCl 
• 76077-77-5 {Mn(O)(tetraphenylporphyrin^(2-))} 
• 210409-38-4 tetrabutylammonium dicyano(meso-tetraphenylporphyrinato)manganate(III) 
• 79408-54-1 (tetraphenylporphyrinato)manganese(III) perchlorate 

Relevant articles and documents

Nitrene Photochemistry of Manganese N-Haloamides**

Manganese complexes supported by macrocyclic tetrapyrrole ligands represent an important platform for nitrene transfer catalysis and have been applied to both C?H amination and olefin aziridination catalysis. The reactivity of the transient high-valent Mn nitrenoids that mediate these processes renders characterization of these species challenging. Here we report the synthesis and nitrene transfer photochemistry of a family of MnIII N-haloamide complexes. The S=2 N-haloamide complexes are characterized by 1H NMR, UV-vis, IR, high-frequency and -field EPR (HFEPR) spectroscopies, and single-crystal X-ray diffraction. Photolysis of these complexes results in the formal transfer of a nitrene equivalent to both C?H bonds, such as the α-C?H bonds of tetrahydrofuran, and olefinic substrates, such as styrene, to afford aminated and aziridinated products, respectively. Low-temperature spectroscopy and analysis of kinetic isotope effects for C?H amination indicate halogen-dependent photoreactivity: Photolysis of N-chloroamides proceeds via initial cleavage of the Mn?N bond to generate MnII and amidyl radical intermediates; in contrast, photolysis of N-iodoamides proceeds via N?I cleavage to generate a MnIV nitrenoid (i.e., {MnNR}7 species). These results establish N-haloamide ligands as viable precursors in the photosynthesis of metal nitrenes and highlight the power of ligand design to provide access to reactive intermediates in group-transfer catalysis.

Method for synthesizing tetraaryl manganese porphyrin through synchronous aldehyde and pyrrole condensation and bivalent manganese salt oxidation insertion reaction

The invention discloses a method for synthesizing tetraaryl manganese porphyrin by synchronous aldehyde and pyrrole condensation and bivalent manganese salt oxidation insertion reaction. Aromatic aldehyde, pyrrole and manganese dichloride are refluxed in

Crystallographic identification of a series of manganese porphyrin complexes with nitrogenous bases

Studying the axial ligation behavior of metalloporphyrins with nitrogenous bases helps to better understand not only the biological function of heme-based protein systems, but also the catalytic properties of porphyrin-based reaction sites in other biomim