345652-13-3

Basic information

• Product Name: bis-<2-(ethylthio)benzyl> oxalate
• Synonyms: bis-<2-(ethylthio)benzyl> oxalate
• CAS NO: 345652-13-3
• Molecular Weight: 390.524
• Mol File: 345652-13-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis-<2-(ethylthio)benzyl> oxalate(CAS DataBase Reference)
• NIST Chemistry Reference: bis-<2-(ethylthio)benzyl> oxalate(345652-13-3)
• EPA Substance Registry System: bis-<2-(ethylthio)benzyl> oxalate(345652-13-3)

Safety Data

• Hazardous Substances Data: 345652-13-3(Hazardous Substances Data)

Upstream product

• 4521-31-7 o-hydroxymethyl thiophenol 
• 79-37-8 oxalyl dichloride 
• 37527-69-8 (2-ethylsulfanyl-phenyl)-methanol 

Downstream Products

• 94636-81-4 1,3-dihydro-1-methylbenzothiophen 
• 6165-55-5 2-methyl-2,3-dihydro-benzo[b]thiophene 
• 611-15-4 1-methyl-2-vinyl-benzene 
• 95-13-6 1-indene 
• 86509-89-9 C₉H₁₁S 

Relevant articles and documents

Intramolecular Reactions of o-Alkoxy- and o-Alkylthio-benzyl Radicals

We report new gas-phase reactions of o-substituted benzyl radicals produced by flash vacuum pyrolysis of 2,3-dihydro-1,3,2-benzoxazaphosph(V)oles (4)-(6), dibenzyl sulphone (8), and dibenzyl oxalates (9)-(11).Both o-ethoxy- and o-methoxy-benzyl radicals rearrange to o-tolualdehyde via intramolecular hydrogen transfer, as shown by experiments using 2-methoxybenzyl radicals. o-Methylthiobenzyl radicals do not give the corresponding thioaldehyde, but produce a mixture of benzocyclobutene and isomeric dihydrobenzothiophens by novel rearrangement reactions. o-Ethylthio- and o-propylthio-benzyl radicals give o-methylstyrene and o-propenyltoluenes respectively as major products.