86509-89-9

Basic information

• Product Name: C₉H₁₁S
• Synonyms: C₉H₁₁S
• CAS NO: 86509-89-9
• Molecular Weight: 151.252
• Mol File: 86509-89-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₉H₁₁S(CAS DataBase Reference)
• NIST Chemistry Reference: C₉H₁₁S(86509-89-9)
• EPA Substance Registry System: C₉H₁₁S(86509-89-9)

Safety Data

• Hazardous Substances Data: 86509-89-9(Hazardous Substances Data)

Upstream product

• 345652-13-3 bis-<2-(ethylthio)benzyl> oxalate 

Relevant articles and documents

Intramolecular Reactions of o-Alkoxy- and o-Alkylthio-benzyl Radicals

We report new gas-phase reactions of o-substituted benzyl radicals produced by flash vacuum pyrolysis of 2,3-dihydro-1,3,2-benzoxazaphosph(V)oles (4)-(6), dibenzyl sulphone (8), and dibenzyl oxalates (9)-(11).Both o-ethoxy- and o-methoxy-benzyl radicals rearrange to o-tolualdehyde via intramolecular hydrogen transfer, as shown by experiments using 2-methoxybenzyl radicals. o-Methylthiobenzyl radicals do not give the corresponding thioaldehyde, but produce a mixture of benzocyclobutene and isomeric dihydrobenzothiophens by novel rearrangement reactions. o-Ethylthio- and o-propylthio-benzyl radicals give o-methylstyrene and o-propenyltoluenes respectively as major products.