345665-10-3

Basic information

• Product Name: (+)-(1R,2R,6R)-2,2,4,4,4-pentachloro-N-[(6-(tert-butyl-dimethylsiloxy)-5-isopropyl-2-methyl-cyclohex-2-enyl)]-N-methyl-butyramide
• CAS NO: 345665-10-3
• Molecular Weight: 539.873
• Mol File: 345665-10-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+)-(1R,2R,6R)-2,2,4,4,4-pentachloro-N-[(6-(tert-butyl-dimethylsiloxy)-5-isopropyl-2-methyl-cyclohex-2-enyl)]-N-methyl-butyramide(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(1R,2R,6R)-2,2,4,4,4-pentachloro-N-[(6-(tert-butyl-dimethylsiloxy)-5-isopropyl-2-methyl-cyclohex-2-enyl)]-N-methyl-butyramide(345665-10-3)
• EPA Substance Registry System: (+)-(1R,2R,6R)-2,2,4,4,4-pentachloro-N-[(6-(tert-butyl-dimethylsiloxy)-5-isopropyl-2-methyl-cyclohex-2-enyl)]-N-methyl-butyramide(345665-10-3)

Safety Data

• Hazardous Substances Data: 345665-10-3(Hazardous Substances Data)

Upstream product

• 242130-27-4 (+)-(1R,2R,5S)-N-benzoyloxy-N-methyl-carbamic acid-4,6,6-trimethyl-bicyclo[3.1.1]hept-3-en-2-yl-ester 
• 242130-26-3 (+)-(3aS,7R,7aR)-7-isopropyl-3,4-dimethyl-3a,6,7,7a-tetrahydro-3H-benzoxazol-2-one 
• 242130-24-1 (+)-(1R,2S,6R)-6-isopropyl-3-methyl-2-methylamino-cyclohex-3-enol 
• 22339-08-8 (+)-trans-verbenol 
• 72060-97-0 2,2,4,4,4-Pentachlorbuttersaeurechlorid 
• 69739-34-0 t-butyldimethylsiyl triflate 

Relevant articles and documents

A short synthesis of (-)-dendrobine. Some observations on the nickel mediated radical cyclisation and on the Pauson-Khand reaction

The total synthesis of (-)-dendrobine was accomplished in 13 steps starting from (+)-verbenol. The key step is a radical cascade starting with a carbamyl radical generated by reaction of the N-benzoyloxy-carbamyl derivative of trans-verbenol with tributyl