242130-24-1

Basic information

• Product Name: (+)-(1R,2S,6R)-6-isopropyl-3-methyl-2-methylamino-cyclohex-3-enol
• Synonyms: (+)-(1R,2S,6R)-6-isopropyl-3-methyl-2-methylamino-cyclohex-3-enol
• CAS NO: 242130-24-1
• Molecular Weight: 183.294
• Mol File: 242130-24-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (+)-(1R,2S,6R)-6-isopropyl-3-methyl-2-methylamino-cyclohex-3-enol(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(1R,2S,6R)-6-isopropyl-3-methyl-2-methylamino-cyclohex-3-enol(242130-24-1)
• EPA Substance Registry System: (+)-(1R,2S,6R)-6-isopropyl-3-methyl-2-methylamino-cyclohex-3-enol(242130-24-1)

Safety Data

• Hazardous Substances Data: 242130-24-1(Hazardous Substances Data)

Upstream product

• 242130-27-4 (+)-(1R,2R,5S)-N-benzoyloxy-N-methyl-carbamic acid-4,6,6-trimethyl-bicyclo[3.1.1]hept-3-en-2-yl-ester 
• 22339-08-8 (+)-trans-verbenol 
• 242130-26-3 (+)-(3aS,7R,7aR)-7-isopropyl-3,4-dimethyl-3a,6,7,7a-tetrahydro-3H-benzoxazol-2-one 

Downstream Products

• 2115-91-5 dendrobine 
• 242130-28-5 (+)-(1S,5R,6S)-N-(6-acetoxy-5-isopropyl-2-methyl-cyclohex-2-enyl)-N-methyl-N-(2-prop-2-ynyl)-amine 
• 242130-43-4 Acetic acid (2aS,4aS,5R,6S,7R,7aS,7bS)-5-cyano-6-isopropyl-1,7b-dimethyl-4-phenoxythiocarbonyloxy-decahydro-cyclopenta[cd]indol-7-yl ester 
• 345665-08-9 (+)-(3R,4R,5R)-4-acetoxy-5-isopropyl-2-methyl-3-(N-methyl-N-trichloroacetylamino)-cyclohex-1-ene 
• 345665-13-6 (+)-(3R,4R,5R)-4-acetoxy-5-isopropyl-2-methyl-3-[(N-methyl-N-pentachlorobutyryl)-amino]-cyclohex-1-ene 
• 345665-10-3 (+)-(1R,2R,6R)-2,2,4,4,4-pentachloro-N-[(6-(tert-butyl-dimethylsiloxy)-5-isopropyl-2-methyl-cyclohex-2-enyl)]-N-methyl-butyramide 
• 345665-15-8 Acetic acid (2aS,6R,7R,7aS,7bR)-6-isopropyl-1,7b-dimethyl-4-oxo-4a-phenylselanyl-decahydro-cyclopenta[cd]indol-7-yl ester 

Relevant articles and documents

A short synthesis of (-)-dendrobine. Some observations on the nickel mediated radical cyclisation and on the Pauson-Khand reaction

The total synthesis of (-)-dendrobine was accomplished in 13 steps starting from (+)-verbenol. The key step is a radical cascade starting with a carbamyl radical generated by reaction of the N-benzoyloxy-carbamyl derivative of trans-verbenol with tributyl