34701-03-6

Basic information

• Product Name: Cyclohexane, 1-bromo-2-iodo-, trans-
• CAS NO: 34701-03-6
• Molecular Formula: C6H10BrI
• Molecular Weight: 288.954
• Mol File: 34701-03-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Cyclohexane, 1-bromo-2-iodo-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, 1-bromo-2-iodo-, trans-(34701-03-6)
• EPA Substance Registry System: Cyclohexane, 1-bromo-2-iodo-, trans-(34701-03-6)

Safety Data

• Hazardous Substances Data: 34701-03-6(Hazardous Substances Data)

Upstream product

• 110-83-8 cyclohexene 
• 29641-86-9 1-chloro-2-iodocyclohexane 

Downstream Products

• 110-83-8 cyclohexene 
• 54826-40-3 benzoic acid-(2-iodo-cyclohexyl ester) 
• 4351-54-6 cyclohexyl formate 
• 144300-25-4 (1R,2R)-1-acetoxy-2-iodocyclohexane 
• 2425-33-4 2-bromocyclocyclohexanol 
• 41049-47-2 trans-1-iodo-2-trifluoroacetoxycyclohexane 
• 931-17-9 1,2-Cyclohexanediol 
• 1072-86-2 (1R,2R)-trans-1,2-cyclohexanediol 

Relevant articles and documents

Polymeric benzyltriethylammonium dichloroiodate and dibromoiodate: Preparation and use as synthetic reagents

Solid phase polymeric analogue of benzyltriethylammonium dichloroiodate and dibromoiodate reagents have been prepared and used as recyclable reagents for synthetic transformations on some organic substrates. The development of these reagents involve polym

BROMO- AND IODOFUNCTIONALIZATION OF OLEFINS BY MEANS OF THE MERCURY(II) SALT-HALOGEN COMBINATION

Mercury(II) salts (fluoride, chloride, bromide, formate, acetate, trifluoroacetate, propionate, benzoate, nitrate, methanesulphonate, toluene-p-sulphonate, thiocyanate, and toluene-p-sulphinate) reacted with monoolefines and bromine or iodine to give 1,2-bifunctionalized products resulting from the addition of the halogen and the mercury(II) salt anion selectively.The addition was regiospecific for styrene and for 3,3-dimethylbut-1-ene affording Markownikoff type products, respectively.In the case of hex-1-ene both regioisomers were obtained.For cyclic alkenes trans-1,2-derivatives were stereoselectively obtained.Cycloocta-1,5-diene gave the monoaddition products.Buta-1,3-diene underwent mainly 1,2-addition and allylic derivatives gave the corresponding 1,2,3-trifunctionalized compounds.A possible ionic mechanism is proposed to explain the obtained addition products.

I(py)2BF4, ein neues Reagens: allgemeine Methode fuer die 1,2-Iodfunktionalisierung von Olefinen

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