35125-65-6Relevant articles and documents
Designing of a Magnetodielectric System in Hybrid Organic–Inorganic Framework, a Perovskite Layered Phosphonate MnO3PC6H4-m-Br?H2O
Basu, Tathamay,Bloyet, Clarisse,Beaubras, Félicien,Caignaert, Vincent,Perez, Olivier,Rueff, Jean-Michel,Pautrat, Alain,Raveau, Bernard,Lohier, Jean-Fran?ois,Jaffrès, Paul-Alain,Couthon, Hélène,Rogez, Guillaume,Taupier, Grégory,Dorkenoo, Honorat
, (2019)
Very few hybrid organic–inorganic framework (HOIF) exhibit direct coupling between spins and dipoles and are also restricted to a particular COOH-based system. It is shown how one can design a hybrid system to obtain such coupling based on the rational design of the organic ligands. The layered phosphonate, MnO3PC6H5?H2O, consisting of perovskite layers stacked with organic phenyl layers, is used as a starting potential candidate. To introduce dipole moment, a closely related metal phosphonate, MnO3PC6H4-m-Br?H2O is designed. For this purpose, this phosphonate is prepared from 3-bromophenylphosphonic acid that features one electronegative bromine atom directly attached on the aromatic ring in the meta position, lowering the symmetry of precursor itself. Thus, bromobenzene moieties in MnO3PC6H4-m-Br?H2O induce a finite dipole moment. This new designed compound exhibits complex magnetism, as observed in layered alkyl chains MnO3PCnH2 n +1?H2O materials, namely, 2D magnetic ordering ≈20 K followed by weak ferromagnetic ordering below 12 K (T1) with a magnetic field (H)-induced transition ≈25 kOe below T1. All these magnetic features are exactly captured in the T and H-dependent dielectric constant, ε′(T) and ε′(H). This demonstrates direct magnetodielectric coupling in this designed hybrid and yields a new path to tune multiferroic ordering and magnetodielectric coupling.
A dual catalytic strategy for carbon-phosphorus cross-coupling via gold and photoredox catalysis
He, Ying,Wu, Hongmiao,Toste, F. Dean
, p. 1194 - 1198 (2015/01/30)
A new method for the P-arylation of aryldiazonium salts with H-phosphonates via dual gold and photoredox catalysis is described. The reaction proceeds smoothly at room temperature in the absence of base and/or additives, and offers an efficient approach t
Evaluation of the amino acid binding site of Mycobacterium tuberculosis glutamine synthetase for drug discovery
Nordqvist, Anneli,Nilsson, Mikael T.,Roettger, Svenja,Odell, Luke R.,Krajewski, Wojciech W.,Evalena Andersson,Larhed, Mats,Mowbray, Sherry L.,Karlen, Anders
, p. 5501 - 5513 (2008/12/20)
A combination of a literature survey, structure-based virtual screening and synthesis of a small library was performed to identify hits to the potential antimycobacterial drug target, glutamine synthetase. The best inhibitor identified from the literature
