35453-12-4

Basic information

• Product Name: Benzene, [[(phenylsulfinyl)methyl]thio]-
• CAS NO: 35453-12-4
• Molecular Formula: C13H12OS2
• Molecular Weight: 248.37
• Mol File: 35453-12-4.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, [[(phenylsulfinyl)methyl]thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[(phenylsulfinyl)methyl]thio]-(35453-12-4)
• EPA Substance Registry System: Benzene, [[(phenylsulfinyl)methyl]thio]-(35453-12-4)

Safety Data

• Hazardous Substances Data: 35453-12-4(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 3561-67-9 bis(phenylthio)methane 

Downstream Products

• 120346-63-6 (E)-3-butyl-2-phenylsulphonyl-2-phenylthiooxirane 
• 120346-64-7 (E)-3-phenyl-2-phenylsulphonyl-2-phenylthiooxirane 
• 120346-62-5 (trans)-3-(1'-methylethyl)-2-phenylsulfonyl-2-phenylthiooxirane 
• 120346-59-0 (E)-1-phenylsulphonyl-1-phenylthiohex-1-ene 
• 120346-60-3 (E)-2-phenyl-1-phenylsulphonyl-1-phenylthioethene 
• 120346-61-4 (E)-3-methyl-2-phenylsulphonyl-2-phenylthiooxirane 
• 120346-58-9 (E)-3-methyl-1-phenylsulphonyl-1-phenylthiobut-1-ene 
• 120346-57-8 (E)-1-phenylsulphonyl-1-phenylthioprop-1-ene 
• 120346-79-4 S-phenyl 2-iodo-2-phenyl(thioethanoate) 
• 120346-75-0 S-phenyl 2-bromo-2-phenyl(thioethanoate) 
• 120346-71-6 S-phenyl 2-chloro-2-phenyl(thioethanoate) 
• 120346-78-3 S-phenyl 2-iodo(thiohexanoate) 
• 120346-74-9 2-Bromo-hexanethioic acid S-phenyl ester 
• 120346-70-5 S-phenyl 2-chloro(thiohexanoate) 

Relevant articles and documents

Ammonium salt catalyzed oxidation of organosulfides to organosulfoxydes

The selective oxidation of aromatic and aliphatic organosulfides with H2O2/H2O catalyzed by metal free ammonium salts has been explored. Reactions were performed using 2.5-5 mol % of catalyst loadings, isolating the corres

1-Butyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate (BAAOD): An efficient and novel reagent for oxidation of sulfides to the corresponding sulfoxides

This article describes an efficient and easy method for oxidation of sulfides 1 to their corresponding sulfoxides 2 with 1-butyl-4-aza-1- azoniabicyclo[2.2.2]octane dichromate (BAAOD) under nonaqueous conditions in high yields.

1-Benzyl-1-aza-4-azoniabicyclooctane periodate as new oxidant for oxidation of thiols and sulfides to the corresponding disulfides and sulfoxides under anhydrous conditions

1-Benzyl-1-aza-4-azoniabicyclooctane periodate (BAABCOP) 1, readily prepared as an orange solid from commercially available DABCO (1,4-diazobicyclooctane) performs oxidation in anhydrous conditions. Under these conditions, thiols are selectively oxidised to disulfides. Sulfides are also oxidised to the corresponding sulfoxides under these conditions.