35531-58-9

Basic information

• Product Name: 1,3-Dithiane, 2-(2-nitrophenyl)-
• CAS NO: 35531-58-9
• Molecular Formula: C10H11NO2S2
• Molecular Weight: 241.335
• Mol File: 35531-58-9.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: 1,3-Dithiane, 2-(2-nitrophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dithiane, 2-(2-nitrophenyl)-(35531-58-9)
• EPA Substance Registry System: 1,3-Dithiane, 2-(2-nitrophenyl)-(35531-58-9)

Safety Data

• Hazardous Substances Data: 35531-58-9(Hazardous Substances Data)

Upstream product

• 505-23-7 1,3 dithiane 
• 98-95-3 nitrobenzene 
• 57529-04-1 2-chloro-1,3-dithiane 
• 552-89-6 2-nitro-benzaldehyde 
• 109-80-8 1.3-propanedithiol 
• 48140-35-8 2-(2-nitrophenyl)-1,3-dioxolane 

Downstream Products

• 53165-22-3 2-(2'-aminophenyl)-1,3-dithiane 
• 496043-83-5 2-[2'-(N-Boc-N-trimethylsilyl-amino)phenyl]-1,3-dithiane 
• 496043-95-9 methyl-[2-(2-oxo-2-phenyl-ethyl)-phenyl]-carbamic acid tert-butyl ester 
• 496043-67-5 2-[2'-(N-benzyl-N-Boc-amino)phenyl]-1,3-dithiane 
• 496043-69-7 2-[2'-(N-tert-butyloxycarbonyl-N-prenylamino)phenyl]-1,3-dithiane 
• 496043-70-0 2-[2'-(N-benzyloxycarbonylamino)phenyl]-1,3-dithiane 
• 496043-71-1 2-[2'-(N-methyloxycarbonylamino)phenyl]-1,3-dithiane 
• 396094-75-0 2-[2'-(N,N-di-tert-butoxycarbonylamino)phenyl]-1,3-dithiane 
• 396094-76-1 1-[2'-(N-Boc-N-methylamino)phenyl]-4-phenylbutan-2-one 
• 396094-78-3 2-[2'-(N-Boc-amino)phenyl]-1,3-dithiane 
• 396094-74-9 2-[2'-(N-Boc-N-methylamino)phenyl]-1,3-dithiane 
• 138343-89-2 tert-butyl 2-phenyl-1H-indole-1-carboxylate 

Relevant articles and documents

A simple and convenient catalytic procedure for the preparation of dithioacetals

A simple procedure for the synthesis of cyclic and acyclic thioacetals from aldehydes is described which employs hydrogen chloride solutions generated from acetyl chloride and methanol. It was observed that the reaction could be carded out using catalytic quantities of acetyl chloride, potentially allowing acid sensitive substrates to be used under these conditions.

Direct anodic (thio)acetalization of aldehydes with alcohols (thiols) under neutral conditions, and computational insight into the electrochemical formation of the acetals

A versatile protocol for the production of acetals/thioacetals by means of direct electrochemical oxidation is developed here under neutral conditions, providing (thio)acetals with good functional group tolerance and a wide scope for both aldehydes and (thio)alcohols. DFT calculations reveal that direct electron transfer from the anode plays a key role in carbonyl activation during this acid free acetalization process.

Thioacetalization of aldehydes and ketones catalyzed by hexabromoacetone

Protection of p-anisaldehydewith 1,3-propanedithiol under UV irradiation without a catalyst resulted in 87% yield of 1,3-dithiane in 20 min. Addition of hexabromoacetone further reduced the reaction time and UV irradiation also accelerated the formation o