357675-06-0

Basic information

• Product Name: methyl (R)-3-[(S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-phenylpropanoate
• Synonyms: methyl (R)-3-[(S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-phenylpropanoate
• CAS NO: 357675-06-0
• Molecular Weight: 264.321
• Mol File: 357675-06-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl (R)-3-[(S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-phenylpropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (R)-3-[(S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-phenylpropanoate(357675-06-0)
• EPA Substance Registry System: methyl (R)-3-[(S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-phenylpropanoate(357675-06-0)

Safety Data

• Hazardous Substances Data: 357675-06-0(Hazardous Substances Data)

Upstream product

• 81703-94-8 methyl (2Z)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]acrylate 
• 98-80-6 phenylboronic acid 
• 66601-82-9 methyl (S)-4,5-dihydroxy-4,5-O-isopropylidene-2-pentenoate 
• 81703-93-7 methyl (2E)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]acrylate 

Downstream Products

• 950838-18-3 (4S,5R)-5-(hydroxymethyl)-4-phenyldihydrofuran-2(3H)-one 

Relevant articles and documents

Stereoselective conjugate addition of aryl- And alkenylboronic acids to acyclic γ,δ-oxygen-substituted α,β-enoates

The substrate-controlled Rh1-catalyzed conjugate addition of aryl- and alkenylboronic acids to α,β-unsaturated esters which bear γ- and δ-oxygen substituents takes place in a highly anti diastereoselective fashion either when using γ-hydroxyl u

A study of conjugate addition to a γ,δ-dioxolanyl-α,β-unsaturated ester

Diastereoselective phenylcuprate addition to (S)-3-(2,2-dimethyl-1,3-dioxolan-4-yl)-trans-2-propenoate has been achieved in the presence of lithium bromide, copper(I) cyanide, trimethylsilyl chloride and dimethylsulfide cocatalysts.