35797-14-9

Basic information

• Product Name: {(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾
• Synonyms: {(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾
• CAS NO: 35797-14-9
• Molecular Weight: 311.214
• Mol File: 35797-14-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: {(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾(CAS DataBase Reference)
• NIST Chemistry Reference: {(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾(35797-14-9)
• EPA Substance Registry System: {(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾(35797-14-9)

Safety Data

• Hazardous Substances Data: 35797-14-9(Hazardous Substances Data)

Upstream product

• 26160-57-6 pentacarbonyl(ethoxyphenylmethylene)chromium⁽⁰⁾ 
• 74-89-5 methylamine 
• 306-37-6 N,N'-Dimethylhydrazine dihydrochloride 
• 27436-93-7 pentacarbonyl(1-methoxybenzylidene)chromium⁽⁰⁾ 

Downstream Products

• 121809-07-2 {(N-benzoyl-N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾ 
• 121809-50-5 pentacarbonyl(DMAP)chromium 
• 122846-95-1 tetracarbonyl{(N-((2,2-dimethylethoxy)carbonyl)-N-methylamino)(phenyl)methylene-C,O}chromium 

Relevant articles and documents

Hydrazinolysis of Fischer-type oxacarbenes made efficient: A new and easy entry to alkyl and aryl hydrazinocarbene complexes

Hydrazinolysis of the pentacarbonyl[alkyl- or aryl-(methoxy)carbene] complexes of W0 and Cr0 with both 1,1- and 1,2-disubstituted hydrazines affords the corresponding new hydrazinocarbenes 15-18, 21 and 22, and the presence of LiCl in the reaction medium greatly increases their yields.

Solution and solid state conformation of Fischer carbene complexes vis-à-vis conformation of aryl carboxamides: Complexation of the aromatic ring by tricarbonylchromium makes a difference

Crystallography and proton NMR spectroscopy were used to compare the conformations of aryl amino Fischer carbene complexes with structurally analogous aryl carboxamides. The similarity disappears when the aromatic rings were complexed with tricarbonylchro