35882-30-5Relevant articles and documents
STEROIDS OF THE SPIROSTAN AND FUROSTAN SERIES FROM Nolina microcarpa III. STRUCTURE OF NOLINOFUROSIDES G AND H
Shevchuk, G. V.,Vollerner, Yu. S.,Shashkov, A. S.,Gorovits, M. B.,Chirva, V. Ya.
, p. 706 - 711 (1991)
Two new glycosides which have been called nolinofurosides G(I) and H(III), have been isolated from the leaves of Nolina microcarpa.Nolinofuroside G is the sodium salt of 26-β-D-glucofuranosyloxy-(25S)-furost-5,20(22)-diene-1β,3β-diol 1-sulfate, and nolinofuroside H is the sodium salt of 1-β-D-fucopyranosyloxy-26-β-D-glucopyranosyloxy-(25S)-furost-5,20(22)-diene-3β-ol 3-sulfate.
STEROIDS OF THE SPIROSTAN AND FUROSTAN SERIES FROM Nolina microcarpa 1. STRUCTURES OF NOLINOSPIROSIDE C AND NOLINOFUROSIDES A AND C
Shevchuk, G. V.,Vollerner, Yu. S.,Shashkov, A. S.,Chirva, V. Ya.
, p. 592 - 597 (1991)
In addition to the known steroid sapogenin (25S)-ruscogenin (I), three new glycosides have been isolated from the leaves of Nolina microcarpa S.Wats. (family Dracaenacea), and the following structures are suggested for them: (25S)-spirost-5-ene-1β,3β-diol 1-O-β-D-fucopyranoside (nolinospiroside C, II), (25S)-furost-5-ene-1β,3β,22α,26-tetraol 1-O-β-D-fucopyranoside (nolinofuroside A, III), and (25S)-furost-5-ene-1β,3β,22α,26-tetraol 1-O-β-D-fucopyranoside 26-O-β-D-glucopyranoside (nolinofuroside C, V).
STEROIDS OF THE FUROSTAN AND SPIROSTAN SERIES FROM Nolina microcarpa II. STRUCTURES OF NOLINOSPIROSIDE D AND NOLINOFUROSIDES D, E, AND F
Shevchuk, G. V.,Vollerner, Yu. S.,Shashkov, A. S.,Chirva, V. Ya.
, p. 597 - 603 (2007/10/02)
Proofs are given of the structures of two new glycosides of the furostan series isolated from the leaves of the plant Nolina microcarpa S.Wats. (family Dracaenaceae).Nolinofuroside D is (25S)-furost-5-ene-1β, 3β,22 α,26-tetraol 1-O-β-D-galactopyranoside 26-O-β-D-glucopyranoside (I), and nolinofuranoside F is (25S)-furost-5-ene-1β,3β,22α,26-tetraol 1-O-β-D-fucopyranoside 26-O-β-D-glucopyranoside 3-O-α-L-rhamnopyranoside (VII).The latter was characterized as its 22-O-methyl ether (VIII).Nolinofuranoside E (IV) has the structure of (25S)-furost-5-ene-1β,3β,22α,26-tetraol 26-O-β-glucopyranoside 1-O- 2)-β-D-fucopyranoside>, which followed from the structure of the fermentation product (VI).The products of the fermentation of the above-named compounds were present in the plant in only trace amounts.Only one of them - nolinospiroside D (III) - has not been described previously.This monoside of the spirostan series is (25S)-spirost-5-ene-1β,3β-diol 1-O-β-D-galactopyranoside.