359015-54-6

Basic information

• Product Name: 2,4-bis(phenylthio)benzaldehyde
• Synonyms: 2,4-bis(phenylthio)benzaldehyde
• CAS NO: 359015-54-6
• Molecular Weight: 322.452
• Mol File: 359015-54-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,4-bis(phenylthio)benzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-bis(phenylthio)benzaldehyde(359015-54-6)
• EPA Substance Registry System: 2,4-bis(phenylthio)benzaldehyde(359015-54-6)

Safety Data

• Hazardous Substances Data: 359015-54-6(Hazardous Substances Data)

Upstream product

• 528-75-6 2,4-dinitrobenzaldehyde 
• 4551-15-9 phenylthiotrimethylsilane 

Downstream Products

• 359015-84-2 2-[2',4'-di(phenylthio)benzyl]pyridine 
• 616230-60-5 2-[α-hydroxy-2',4'-di(phenylthio)benzyl]benzothiazole 
• 616230-58-1 2-[α-hydroxy-2',4'-di(phenylthio)benzyl]benzoxazole 
• 359015-67-1 2-[α-hydroxy-2,4-di(phenylthio)benzyl]pyridine 

Relevant articles and documents

Efficient synthesis of unsymmetrical diaryl thioethers via TBAF-mediated denitrative substitution of nitroarenes with PhSTMS under mild and neutral conditions

Tetrabutylammonium fluoride (TBAF) effectively facilitated a denitrative substitution reaction of electron-deficient nitroarenes with phenylthiotrimethylsilane (PhSTMS) under mild and base-free neutral conditions at room temperature, providing a practical and efficient synthesis of useful unsymmetrical diaryl thioethers. Nitroarenes bearing ortho- and para-positioned electron-withdrawing groups are the most reactive substrates, indicating that this reaction most possibly proceeded via the nucleophilic aromatic substitution (SNAr) mechanism.