35920-23-1

Basic information

• Product Name: N-(4-bromophenyl)-N-nitrosoacetamide
• CAS NO: 35920-23-1
• Molecular Formula: C₈H₇BrN₂O₂
• Molecular Weight: 243.0574
• Mol File: 35920-23-1.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 310.9°C at 760 mmHg
• Flash Point: 141.8°C
• Density: 1.57g/cm³
• Vapor Pressure: 0.000583mmHg at 25°C
• Refractive Index: 1.6
• CAS DataBase Reference: N-(4-bromophenyl)-N-nitrosoacetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-bromophenyl)-N-nitrosoacetamide(35920-23-1)
• EPA Substance Registry System: N-(4-bromophenyl)-N-nitrosoacetamide(35920-23-1)

Safety Data

• Hazardous Substances Data: 35920-23-1(Hazardous Substances Data)

Upstream product

• 938-81-8 N-nitrosoacetanilide 
• 754-05-2 ethenyltrimethylsilane 
• 103-88-8 4-bromoacetanilide 

Downstream Products

• 92-66-0 4-bromo-1,1'-biphenyl 
• 1927-95-3 4-bromophenyl acetate 
• 103-88-8 4-bromoacetanilide 
• 763910-59-4 N-(4-bromo-phenyl)-N-nitroso-hydroxylamine 
• 2039-82-9 1-bromo-4-ethenyl-benzene 
• 94397-78-1 (E)-trimethyl<2-(4-bromophenyl)ethenyl>silane 
• 94397-81-6 [1-(4-Bromo-phenyl)-vinyl]-trimethyl-silane 
• 13041-70-8 (E)-4-bromostilbene 
• 17110-57-5 p-Bromodiazoaniline 
• 36966-93-5 4-bromo-benzene-standarddiazohydroxide-⁽¹⁾ 
• 63996-36-1 2-(4-bromophenyl]pyridine 
• 39795-60-3 4-(4-bromophenyl)pyridine 

Relevant articles and documents

Conversion of N-aromatic amides to O-aromatic esters

(Matrix Presented) N-Aromatic secondary amides can be transformed into O-aromatic esters in high yield via N-nitrosamide intermediates. The amides can be generated in situ from the corresponding aromatic amines or nitro compounds, and phenols can easily be made from the esters. The reaction can be modified by addition of methyl methacrylate or toluene at 0 °C to give polymerization or deamination, respectively. The rearrangement mechanism may involve radical formation and recombination.