94397-81-6

Basic information

• Product Name: [1-(4-Bromo-phenyl)-vinyl]-trimethyl-silane
• Synonyms: [1-(4-Bromo-phenyl)-vinyl]-trimethyl-silane
• CAS NO: 94397-81-6
• Molecular Weight: 255.23
• Mol File: 94397-81-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [1-(4-Bromo-phenyl)-vinyl]-trimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: [1-(4-Bromo-phenyl)-vinyl]-trimethyl-silane(94397-81-6)
• EPA Substance Registry System: [1-(4-Bromo-phenyl)-vinyl]-trimethyl-silane(94397-81-6)

Safety Data

• Hazardous Substances Data: 94397-81-6(Hazardous Substances Data)

Upstream product

• 938-81-8 N-nitrosoacetanilide 
• 35920-23-1 acetic acid-(4-bromo-N-nitroso-anilide) 
• 673-40-5 4-bromobenzenediazonium tetrafluoroborate 
• 754-05-2 ethenyltrimethylsilane 

Relevant articles and documents

Stereospecific Arylation of Alkenylsilanes with Arylpalladium Acetates

Alkenyltrimethylsilanes ((E)- and (Z)-RCH=CHSiMe3: R = H, Ph, n-C6H13 and CH3OCH2) stereospecifically reacted at 40 deg C or room temperature with in situ generated phenylpalladium acetate to produce R(Ph)C=CSiMe3 and RCH=C(Ph)SiMe3 with inversion of their geometry.The arylation of CH2=CHSiMe3 with arylpalladium acetates gave (E)-ArCH=CHSiMe3 (Ar = XPH; X = H, 4-Me, 4-MeO, 4-Br, 4-I, 4-EtOCO, and 4-NO2) in good yields.