35998-47-1

Basic information

• Product Name: acetic acid-(2-chloro-cyclohexyl ester)
• Synonyms: acetic acid-(2-chloro-cyclohexyl ester)
• CAS NO: 35998-47-1
• Molecular Weight: 176.643
• Mol File: 35998-47-1.mol
• Article Data: 30

Chemical Properties

• CAS DataBase Reference: acetic acid-(2-chloro-cyclohexyl ester)(CAS DataBase Reference)
• NIST Chemistry Reference: acetic acid-(2-chloro-cyclohexyl ester)(35998-47-1)
• EPA Substance Registry System: acetic acid-(2-chloro-cyclohexyl ester)(35998-47-1)

Safety Data

• Hazardous Substances Data: 35998-47-1(Hazardous Substances Data)

Upstream product

• 108-22-5 Isopropenyl acetate 
• 6628-80-4 trans-2-chlorocyclohexanol 
• 286-20-4 cyclohexane-1,2-epoxide 
• 75-36-5 acetyl chloride 
• 64-19-7 acetic acid 
• 110-83-8 cyclohexene 
• 127-19-5 N,N-dimethyl acetamide 
• 108-24-7 acetic anhydride 
• 822-87-7 2-Chlorocyclohexanone 
• 27334-16-3 trans-2-chlorocyclohexyltellurium trichloride 
• 7080-50-4 chloramine T trihydrate 
• 127-65-1 chloroamine-T 
• 14248-14-7 (+/-)-trans-1-acetoxy-2-(toluene-4-sulfonyloxy)-cyclohexane 
• 86703-56-2 cis-1-acetoxycyclohexane-2-ol 

Downstream Products

• 399-32-6 acetic acid-(2-fluoro-cyclohexyl ester) 
• 931-13-5 cis-(1R,2S)-2-chlorocyclohexanol 
• 931-17-9 1,2-Cyclohexanediol 
• 2441-97-6 3-chloro-cyclohexene 
• 930-66-5 1-chlorocyclohexene 
• 1165952-91-9 cyclohexa-1,3-diene 
• 1759-71-3 trans-1,2-cyclohexanediol diacetate 
• 2396-76-1 cis-1,2-diacetoxycyclohexane 
• 110-83-8 cyclohexene 

Relevant articles and documents

A facile 1,2-acetoxychlorination reaction of olefins by using the N,N-dimethtylacetamide/hydrogen chloride/m-chloroperbenzoic acid (or oxone) system

Various alkenes underwent 1,2-acetoxychlorination by dimethylacetamide (DMA)/HCl/m-CPBA (or Oxone) system in good yields.

Phase-transfer and other types of catalysis with cyclopropenium ions

Abstract This work establishes the cyclopropenium ion as a viable platform for efficient phase-transfer catalysis of a diverse range of organic transformations. The amenability of these catalysts to large-scale synthesis and structural modification is demonstrated. Evaluation of the molecular structure of an optimal catalyst reveals some unique structural features of these systems. Finally, a discussion of electronic charge distribution underscores an important consideration for catalyst design. Aromatic ions: Tris(dialkylamino)cyclopropenium ions are shown to be effective carbocationic phase-transfer catalysts for a variety of mainstay transformations. The cyclopropenium platform is shown to be modular and accessible on scale. An X-ray structure and electron-density map revealed some unique features of this architecture (see scheme).

Convenient synthesis of chlorohydrins from epoxides using zinc oxide: Application to 5,6-epoxysitosterol

Efficient synthesis of protected and unprotected chlorohydrins has been achieved by ring opening of epoxides with acetyl/benzoyl chloride and TMSCl using a catalytic amount of ZnO as a reusable catalyst. The applicability of ZnO is further extended by performing the cleavage of the natural product 5,6-epoxysitosterol with acetyl chloride.