3603-86-9

Basic information

• Product Name: 1,2-Cycloheptanedicarboxylic acid, cis-
• CAS NO: 3603-86-9
• Molecular Formula: C9H14O4
• Molecular Weight: 186.208
• Mol File: 3603-86-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2-Cycloheptanedicarboxylic acid, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Cycloheptanedicarboxylic acid, cis-(3603-86-9)
• EPA Substance Registry System: 1,2-Cycloheptanedicarboxylic acid, cis-(3603-86-9)

Safety Data

• Hazardous Substances Data: 3603-86-9(Hazardous Substances Data)

Upstream product

• 3603-85-8 Cyclohept-2-en-1,2-dicarbonsaeure 
• 623-11-0 1-methyl-4-nitrosobenzene 
• 101170-99-4 (+/-)-trans-cycloheptane-1,2-dicarboxylic acid diethyl ester 
• 99181-53-0 (+/-)-trans-2-acetyl-cycloheptanecarboxylic acid 
• 2809-78-1 1-ethynylcycloheptanol 
• 14377-11-8 1-acetyl-1-cycloheptene 
• 3603-86-9 trans-cycloheptane-1,2-dicarboxylic acid 
• 20343-19-5 cyclohept-1-enecarbonitrile 
• 151-50-8 potassium cyanide 

Downstream Products

• 3603-86-9 trans-cycloheptane-1,2-dicarboxylic acid 
• 3603-86-9 trans-cycloheptane-1,2-dicarboxylic acid 
• 13553-19-0 (1S,2S)-cycloheptane-1,2-diol 
• 101429-60-1 (+/-)-trans-2-phenylacetyl-cycloheptanecarboxylic acid 

Relevant articles and documents

Absolute configuration of trans-perhydroazulene

We present the absolute configuration (AC) determination of an alkane, trans-perhydroazulene (1), that displays the naturally very common trans fused [5,7] ring system. We outline the first synthesis yielding enantiopure 1 and the application of optical rotatory dispersion (ORD) and vibrational circular dichroism (VCD) techniques. The spectroscopic results are in excellent agreement with the computed ORD at B3LYP/6-311++G(2d,2p) and the computed VCD spectrum at B3LYP/6-311++G(d,p), providing an assignment of the AC as (R,R)-(+)-1.