36789-29-4

Basic information

• Product Name: N-(2,4-dibromo-5-methylphenyl)acetamide
• CAS NO: 36789-29-4
• Molecular Formula: C₉H₉Br₂NO
• Molecular Weight: 306.9819
• Mol File: 36789-29-4.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 386.8°C at 760 mmHg
• Flash Point: 187.8°C
• Density: 1.793g/cm³
• Vapor Pressure: 3.44E-06mmHg at 25°C
• Refractive Index: 1.627
• CAS DataBase Reference: N-(2,4-dibromo-5-methylphenyl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2,4-dibromo-5-methylphenyl)acetamide(36789-29-4)
• EPA Substance Registry System: N-(2,4-dibromo-5-methylphenyl)acetamide(36789-29-4)

Safety Data

• Hazardous Substances Data: 36789-29-4(Hazardous Substances Data)

Upstream product

• 90914-81-1 4-bromo-3-methylacetanilide 
• 67643-51-0 2,4-dibromo-5-methylaniline 
• 108-24-7 acetic anhydride 
• 36789-28-3 C₁₀H₁₂BrNO₂S 
• 537-92-8 3-Methylacetanilide 
• 31543-75-6 2,4-dibromotoluene 
• 6933-10-4 amino-5-bromo-2-toluene 
• 615-36-1 2-bromoaniline 
• 65854-92-4 N-(2-bromophenyl)-2,2-dimethylpropanamide 
• 34617-87-3 5-methyl-2-(methylsulphinyl)acetophenone 
• 1964-27-8 1-(5-methyl-2-methylsulfanyl-phenyl)-ethanone 
• 860753-33-9 1,5-dibromo-2-methyl-4-nitrobenzene 
• 7726-95-6 bromine 
• 64-19-7 acetic acid 

Downstream Products

• 4793-29-7 2,4-dibromo-5-sulfamoylbenzoic acid 
• 13321-76-1 2,4-dibromo-5-methylphenol 
• 67643-51-0 2,4-dibromo-5-methylaniline 

Relevant articles and documents

Rhodium-Catalyzed ortho-Bromination of O-Phenyl Carbamates Accelerated by a Secondary Amide-Pendant Cyclopentadienyl Ligand

It has been established that a newly developed cyclopentadienyl rhodium(III) [CpARhIII] complex, bearing an acidic secondary amide moiety on the Cp ring, is able to catalyze the ortho-bromination of O-phenyl carbamates with N-bromosuccinimide (NBS) at room temperature. The presence of the acidic secondary amide moiety on the CpA ligand accelerates the bromination by the hydrogen bond between the acidic NH group of the CpA ligand and the carbonyl group of NBS.

BENZIMIDAZOLE ANTIVIRAL AGENTS

Provided are compounds of Formula (I) and (II) and pharmaceutically acceptable salts thereof, their pharmaceutical compositions, their methods of preparation, and their use for treating viral infections mediated by a member of the Flaviviridae family of viruses such as hepatitis C virus (HCV).

Solvent free catalytic C-H functionalisation

Solvent-free reaction conditions facilitate a range of aromatic C-H functionalisations that traditionally require acidic or disfavoured solvents. These reactions include selective ortho- and meta-arylation of aryl carbamates and anilides and selective halogenation reactions. The Royal Society of Chemistry 2010.