36971-11-6Relevant articles and documents
Allylzinc Reagent Additions in Aqueous Media
Petrier, Christian,Luche, Jean-Louis
, p. 910 - 912 (1985)
Homoallylic alcohols are obtained when allylic halides, zinc, and aldehydes or ketones in aqueous media are subjected to ultrasonic waves.
[bmim][Br] as an Inexpensive and Efficient Medium for the Barbier-Type Allylation Reaction Using a Catalytic Amount of Indium: Mechanistic Studies
Dey, Papiya,Koli, Mrunesh,Goswami, Dibakar,Sharma, Anubha,Chattopadhyay, Subrata
, p. 1333 - 1341 (2018/04/02)
Barbier-type allylation reactions of aldehydes and ketones have been carried out with both unsubstituted and γ-substituted allyl bromides using only a catalytic amount (0.1 equiv.) of In metal in [bmim][Br], but not in H2O, organic solvents, or
Ni-catalyzed activation of α-chloroesters: a simple method for the synthesis of α-arylesters and β-hydroxyesters
Durandetti, Muriel,Gosmini, Corinne,Périchon, Jacques
, p. 1146 - 1153 (2007/10/03)
Coupling reactions of α-chloroesters with aryl halides (α-arylation) or carbonyl compounds (Reformatsky) using nickel catalyst allow, under mild conditions, the preparation of various functionalized aryl propionic acid derivatives or β-hydroxyesters. In the synthesis of aryl propionic acid derivatives, the process is efficient with aryl halides bearing either electron-withdrawing or electron-donating groups.
The employment of indium nanoparticles in Barbier-type reaction of allylic chloride in water
Li, Jiaming,Zha, Zhenggen,Sun, Lilin,Zhang, Yan,Wang, Zhiyong
, p. 498 - 499 (2007/10/03)
Indium nanoparticles have been employed in the reactions of various carbonyl compounds with allyl (crotyl) chloride in water, affording the corresponding alcohols with high yields. The crotylation gave exclusive γ-adducts with a dominant syn-isomer. Copyr
