3708-37-0

Basic information

• Product Name: Propanedioic acid, (3-phenyl-2-propenyl)-, dimethyl ester
• CAS NO: 3708-37-0
• Molecular Formula: C14H16O4
• Molecular Weight: 248.279
• Mol File: 3708-37-0.mol
• Article Data: 29

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, (3-phenyl-2-propenyl)-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, (3-phenyl-2-propenyl)-, dimethyl ester(3708-37-0)
• EPA Substance Registry System: Propanedioic acid, (3-phenyl-2-propenyl)-, dimethyl ester(3708-37-0)

Safety Data

• Hazardous Substances Data: 3708-37-0(Hazardous Substances Data)

Upstream product

• 103-54-8 cinnamyl acetate 
• 108-59-8 malonic acid dimethyl ester 
• 104-54-1 3-Phenylpropenol 
• 609-02-9 methyl-malonic acid dimethylester 
• 18424-76-5 sodiodimethylmalonate 
• 124517-47-1 cinnamyl tert-butyl carbonate 
• 7217-71-2 1-phenyl-2-propenyl acetate 
• 85217-69-2 cinnamyl methyl carbonate 
• 2687-12-9 cinnamyl chloride 
• 4392-24-9 3-bromo-1-phenyl-1-propenyl bromide 
• 160879-62-9 methyl 1-phenylprop-2-enyl carbonate 
• 86537-61-3 ethyl cinnamylcarbonate 
• 18424-76-5 dimethyl malonate sodium salt 

Downstream Products

• 17920-83-1 5-phenyl-4-pentenoic acid 
• 1338246-81-3 C₆H₅CHCHCH₂C(C(O)OCH₃)2CHCC(CH₃)2 
• 1412894-90-6 dimethyl 3-benzylcyclopentane-1,1-dicarboxylate 

Relevant articles and documents

Kinetico-mechanistic insights on the assembling dynamics of allyl-cornered metallacycles: The Pt-Npy bond is the keystone

The square-like homo- and heterometallamacrocycles [{Pd(η3-2-Me-C3H4)(Ln)2}2{M(dppp)}2](CF3SO3)6 (dppp = 1,3-bis(diphenylphosphino)propane) and [

Nickel(II) and Palladium(II) complexes of the small-bite-angle p-stereogenic diphosphine ligand MaxPHOS and Its monosulfide

Coordination studies of the optically pure diphosphine ligand (t-Bu) 2P(NH)P(t-BuMe) (MaxPHOS) and its monosulfide with several Pd and Ni moieties are described. Treatment of a solution of MaxPHOS·HBF 4 with [M(acac)2] (M

Efficient stereochemical communication in phosphine-amine palladium-complexes: Exploration of N-substituent effects in coordination chemistry and catalysis

Six-membered chelate complexes of type [Pd(1a-e)Cl2] (2a-e) and [Pd(1a-e)(η3-PhCHCHCHPh)]BF4 (3a-e) of a series of systematically varied chiral phosphine-amine ligands (S,S)-Ph2PCH(CH3)CH2C

Sugar-annulated oxazoline ligands: A novel Pd(II) complex and its application in allylic substitution

Two novel carbohydrate-derived pyridyl (PYOX)- and cyclopropyl (CYBOX)-substituted oxazoline ligands were prepared from D-glucosamine hydrochloride and 1,3,4,6-tetra-O-acetyl-2-amino-2-deoxy-β-D-glucopyranose hydrochloride in two steps, respectively. The sugar-annulated PYOX ligand formed a stable metal complex with Pd(II), which was fully characterized by NMR spectroscopy and X-ray crystallography. NMR and X-ray analysis revealed a change of the conformation in the sugar moiety upon complexation with the palladium(II) species. Both glycosylated ligands resulted in high asymmetric induction (up to 98% ee) upon application as chiral ligands in the Pd-catalyzed allylic alkylation of rac-1,3-diphenylallyl acetate with dimethyl malonate (Tsuji-Trost reaction). Both ligands provided mainly the (R)-enantiomer of the alkylation product.