38042-74-9 Usage
General Description
1-Benzyl-3-Bromopyrrolidine is a chemical compound with a molecular formula of C12H14BrN. It generally exists as a solid, crystalline substance with the melting point and boiling point not readily available, suggesting that it might exhibit variable physical properties under different conditions. This organic compound is primarily characterized by the presence of a nitrogen-containing ring structure called pyrrolidine, attached to two distinct groups: a benzyl group and a bromine atom. The presence of these functional groups implies that 1-Benzyl-3-Bromopyrrolidine may exhibit a range of chemical reactions, making it potentially useful in various applications in the field of organic chemistry. Its potential risks and safety measures aren't publicly stated, indicating that detailed consideration is necessary when handling or storing this substance.
Check Digit Verification of cas no
The CAS Registry Mumber 38042-74-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,8,0,4 and 2 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 38042-74:
(7*3)+(6*8)+(5*0)+(4*4)+(3*2)+(2*7)+(1*4)=109
109 % 10 = 9
So 38042-74-9 is a valid CAS Registry Number.
InChI:InChI=1/C11H14BrN/c12-11-6-7-13(9-11)8-10-4-2-1-3-5-10/h1-5,11H,6-9H2
38042-74-9Relevant articles and documents
Stereocontrolled synthesis of 1,2-dialkyl-4-halopyrrolidines through PhSeX-induced cyclization of secondary homoallylamines
Outurquin, Francis,Pannecoucke, Xavier,Berthe, Benedicte,Paulmier, Claude
, p. 1007 - 1014 (2007/10/03)
The selenium-induced cyclization of α-alkyl or α,α-dialkylhomoallyl-benzylamines 1 by use of PhSeX (X = Cl, Br, I; 1.5 equiv.) provided a mixture of (phenylselanylmethyl)azetidines 2 and (phenylselanyl)pyrrolidines 3.[1] When an excess of PhSeX (X = Cl, Br) was used, 4-halopyrrolidines 4 (X = Cl) or 5 (X = Br) were formed and isolated in very good yields. Mono- or dialkyl 4-halopyrrolidines 4 and 5 could also be obtained stereospecifically by SO2Cl2 or Br2 treatment of 4-(phenylselanylmethyl)azetidines 2, by way of the intermediate (halomethyl)azetidines 14 (X = Cl) or 15 (X = Br). When starting from 4-(phenylselanyl)pyrrolidines 3, monoalkylated 4-halopyrrolidines 4 or 5 could be obtained stereospecifically after decomposition of the unstable dihaloselenuranes 16 and 17. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.
