38053-74-6

Basic information

• Product Name: Silane, trichloro[(1S)-1-phenylethyl]-
• CAS NO: 38053-74-6
• Molecular Formula: C8H9Cl3Si
• Molecular Weight: 239.604
• Mol File: 38053-74-6.mol
• Article Data: 43

Chemical Properties

• CAS DataBase Reference: Silane, trichloro[(1S)-1-phenylethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trichloro[(1S)-1-phenylethyl]-(38053-74-6)
• EPA Substance Registry System: Silane, trichloro[(1S)-1-phenylethyl]-(38053-74-6)

Safety Data

• Hazardous Substances Data: 38053-74-6(Hazardous Substances Data)

Upstream product

• 7787-82-8 Trichloro-(1-chloro-ethyl)-silane 
• 71-43-2 benzene 
• 7446-70-0 aluminium trichloride 
• 100-42-5 styrene 
• 75-79-6 Methyltrichlorosilane 
• 10025-78-2 trichlorosilane 
• 7440-05-3 palladium 

Downstream Products

• 1445-91-6 (S)-1-phenylethanol 
• 17961-78-3 α-methylbenzyl(trimethyl)silane 
• 1517-69-7 (R)-1-phenylethanol 
• 98-85-1 1-Phenylethanol 
• 60-12-8 2-phenylethanol 
• 98-85-1 rel-(R)-1-phenethanol 
• 18292-20-1 β-phenethylsilane 

Relevant articles and documents

Cyclization of o-Allylstyrene via Hydrosilylation: Mechanistic Aspects of Hydrosilylation of Styrenes Catalyzed by Palladium-Phosphine Complexes

Hydrosilylation of o-allylstyrene with trichlorosilane in the presence of 0.3 mol % of a palladium catalyst bearing triphenylphosphine gave trans-1-methyl-2-(trichlorosilylmethyl)indan, l-(2-(2-propenyl)phenyl)-1-trichlorosilylethane, and 1-(2-((E)-1-propenyl)phenyl)-1-trichlorosilylethane. The reaction of styrene with trichlorosilane gave a quantitative yield of 1-phenyl-1-(trichlorosilyl)ethane while allylbenzene did not give silylation products under the same reaction conditions. These results show that the hydropalladation process is operative in the hydrosilylation of styrene derivatives with trichlorosilane catalyzed by palladium-phosphine complexes.

Chiral Bisphosphine BINAP-Stabilized Gold and Palladium Nanoparticles with Small Size and Their Palladium Nanoparticle-Catalyzed Asymmetric Reaction

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Axially Chiral Biaryl Monophosphine Oxides Enabled by Palladium/WJ-Phos-Catalyzed Asymmetric Suzuki-Miyaura Cross-coupling

A highly enantioselective palladium/WJ-Phos-catalyzed Suzuki-Miyaura coupling reaction for efficient construction of axially chiral biaryl monophosphine oxides was developed. A series of axially chiral biaryl monophosphine oxides were obtained in good yields and with high enantioselectivities. The practicability of this reaction was validated in the straightforward synthesis of axially chiral biaryl monophosphine ligand and demonstrated by a 100-g-scale synthesis. Moreover, various functionalizations of the product make it as a platform molecule for synthesis of other chiral biaryl phosphines.

Asymmetric Synthesis of Axially Chiral 2-Aminobiaryls by Rhodium-Catalyzed Benzannulation of 1-Arylalkynes with 2-(Cyanomethyl)phenylboronates

Asymmetric benzannulation of 1-arylalkynes, where the aryl group is an ortho-substituted aromatic group, with 2-(cyanomethyl)phenylboronate was catalyzed by a rhodium complex coordinated with a chiral diene ligand to give high yields of axially chiral 2-aminobiaryls with greater than 90 % ee.