38447-05-1

Basic information

• Product Name: 2,4-Pentadienoic acid, 5-phenyl-, methyl ester, (Z,E)-
• CAS NO: 38447-05-1
• Molecular Formula: C12H12O2
• Molecular Weight: 188.226
• Mol File: 38447-05-1.mol
• Article Data: 67

Chemical Properties

• CAS DataBase Reference: 2,4-Pentadienoic acid, 5-phenyl-, methyl ester, (Z,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Pentadienoic acid, 5-phenyl-, methyl ester, (Z,E)-(38447-05-1)
• EPA Substance Registry System: 2,4-Pentadienoic acid, 5-phenyl-, methyl ester, (Z,E)-(38447-05-1)

Safety Data

• Hazardous Substances Data: 38447-05-1(Hazardous Substances Data)

Upstream product

• 67629-62-3 methyl 4-(diethylphosphono)crotonate 
• 100-52-7 benzaldehyde 
• 100-42-5 styrene 
• 689-89-4 (2E,4E)-methylhexa-2,4-dienoate 
• 14371-10-9 (E)-3-phenylpropenal 
• 5927-18-4 trimethyl phosphonoacetate 
• 104-55-2 3-phenyl-propenal 
• 292638-85-8 acrylic acid methyl ester 
• 536-74-3 phenylacetylene 
• 67-56-1 methanol 
• 28010-12-0 5-phenylpenta-2,4-dienoic acid 
• 24676-98-0 diethyl 3-methoxycarbonyl-2-propenylidenephosphonate 
• 139005-35-9 C₁₂H₉O₃^(1-)*K⁽¹⁺⁾ 
• 2136-75-6 (triphenylphosphoranylidene)acetaldehyde 

Downstream Products

• 77722-62-4 3-ethyl-7-phenyl-hepta-4,6-dien-3-ol 
• 23848-94-4 1t.4-diphenyl-pentadien-(1.3ξ)-oic acid-(5) 
• 251635-75-3 trans-1,3,5-triphenylpent-4-en-1-one 
• 34271-65-3 (2E,4E)-5-phenylpenta-2,4-dienamide 
• 67203-44-5 (+/-)-6c-phenyl-cyclohex-4-ene-1r,2t,3c-tricarboxylic acid-1,2-anhydride-3-methyl ester 
• 67203-44-5 (+/-)-6c-phenyl-cyclohex-4-ene-1r,2c,3c-tricarboxylic acid-1,2-anhydride-3-methyl ester 
• 670254-20-3 (2E,4E)-N-methyl-5-phenylpenta-2,4-dienamide 
• 17237-50-2 2-(4-chloro-phenyl)-3-phenyl-3,6-dihydro-2H-[1,2]oxazine-6-carboxylic acid methyl ester 
• 24239-89-2 2,6-diphenyl-3,6-dihydro-2H-[1,2]oxazine-3-carboxylic acid methyl ester 
• 24239-88-1 2,3-diphenyl-3,6-dihydro-2H-[1,2]oxazine-6-carboxylic acid methyl ester 
• 58506-33-5 5-phenylpenta-2,4-dien-1-ol 
• 117854-09-8 (E)-5-((2R,5S)-5-Isopropyl-3,6-dimethoxy-2,5-dihydro-pyrazin-2-yl)-5-phenyl-pent-3-enoic acid methyl ester 
• 38448-84-9 methyl (2E,4Z)-5-phenyl-2,4-pentadienoate 

Relevant articles and documents

Visible Light Induced Br?nsted Acid Assisted Pd-Catalyzed Alkyl Heck Reaction of Diazo Compounds and N-Tosylhydrazones

A mild visible light-induced palladium-catalyzed alkyl Heck reaction of diazo compounds and N-tosylhydrazones is reported. A broad range of vinyl arenes and heteroarenes with high functional group tolerance, as well as a range of different diazo compounds, can efficiently undergo this transformation. This method features Br?nsted acid-assisted generation of hybrid palladium C(sp3)-centered radical intermediate, which allowed for new selective C?H functionalization protocol.

Ruthenium-Catalyzed Oxidative Cross-Coupling Reaction of Activated Olefins with Vinyl Boronates for the Synthesis of (E, E)-1,3-Dienes

An oxidative cross-coupling reaction between activated olefins and vinyl boronate derivatives has been developed for the highly stereoselective construction of synthetically useful (E,E)-1,3-dienes. The highlight of this reaction is that exclusive stereoselectivity (only E,E-isomer) was achieved from a base-free, ligand-free, and mild catalytic condition with a less expensive [RuCl2(p-cymene)]2 catalyst.

Hydroperoxidations of Alkenes using Cobalt Picolinate Catalysts

Hydroperoxides were synthesized in one step from various alkenes using Co(pic)2as the catalyst with molecular oxygen and tetramethyldisiloxane (TMDSO). The hydration product could be obtained using a modified catalyst, Co(3-mepic)2, with molecular oxygen and phenylsilane. Formation of hydroperoxides occurred through a rapid Co-O bond metathesis of a peroxycobalt compound with isopropanol.