38452-13-0Relevant articles and documents
Hypervalent iodine(III) oxidation catalyzed by quaternary ammonium salt in miceliar systems
Tohma, Hirofumi,Takizawa, Shinobu,Watanabe, Hiroaki,Kita, Yasuyuki
, p. 4547 - 4550 (1998)
Catalytic activation of iodosobenzene (PhI=O) by cetyltrimethylammonium bromide (CTAB) allows sulfide oxidation reaction to occur in high yields under mild conditions in a variety of solvents. This PhI=O activation may be due to the formation of micellar
Extending aromatic acids on TiO2 for cooperative photocatalysis with triethylamine: Violet light-induced selective aerobic oxidation of sulfides
Lang, Xianjun,Li, Hui,Li, Xia,Sheng, Wenlong,Zhou, Jun
supporting information, (2022/01/11)
Designing visible light photocatalysts with a metal oxide semiconductor as the starting material could expand a new horizon for the conversion and storage of solar energy. Here, the benchmark photocatalyst TiO2 was used to pursue this goal by a
A {Ti6W4}-Cluster-Substituted Polyoxotungstate: Synthesis, Structure, and Catalytic Oxidation Properties
Li, Hai-Lou,Lian, Chen,Yang, Guo-Yu
supporting information, p. 14622 - 14628 (2021/10/01)
A novel Ti-W-O-cluster-substituted tungstoantimonate (TA), [H2N(CH3)2]3Na4H9[{Ti6W4O18(OH)(H2O)3}(B-α-SbW9O33)3]·20H2O (1), has been made by hydrothermal reactions of trivacant [B-α-SbW9O33]9- units, Ti4+ cations, and WO42- anions in the presence of [H2N(CH3)2]·Cl and structurally characterized. Intriguingly, the polyoxoanion of 1 is constructed from three [B-α-SbW9O33]9- units and a previously unobserved decanuclear heterometallic Ti-W-O cluster [Ti6W4O18(OH)(H2O)3]11+ ({Ti6W4}) that is comprised of an octahedral [Ti6WO6(H2O)3]18+ cluster and an edge-sharing [W3O12(OH)]7- fragment via six W-O-Ti/W linkers. Furthermore, studies on the catalytic oxidation properties reveal that 1 possesses good catalytic activity toward the oxidation reactions of various sulfides and cyclooctene based on the environmentally friendly oxidant H2O2.