38752-99-7

Basic information

• Product Name: 8,13,13b,14-tetrahydroindolo[2',3':3,4]pyrido[1,2-b]isoquinolin-5(7H)-one
• Synonyms: 8,13,13b,14-tetrahydroindolo[2',3':3,4]pyrido[1,2-b]isoquinolin-5(7H)-one
• CAS NO: 38752-99-7
• Molecular Formula: C19H16N2O
• Molecular Weight: 288.34314
• Mol File: 38752-99-7.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 8,13,13b,14-tetrahydroindolo[2',3':3,4]pyrido[1,2-b]isoquinolin-5(7H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: 8,13,13b,14-tetrahydroindolo[2',3':3,4]pyrido[1,2-b]isoquinolin-5(7H)-one(38752-99-7)
• EPA Substance Registry System: 8,13,13b,14-tetrahydroindolo[2',3':3,4]pyrido[1,2-b]isoquinolin-5(7H)-one(38752-99-7)

Safety Data

• Hazardous Substances Data: 38752-99-7(Hazardous Substances Data)

Upstream product

• 136408-31-6 β-(3-indolyl)ethyl iodide 
• 111563-17-8 2-(2-(1H-indol-3-yl)ethyl)isoquinolin-2-ium iodide 
• 119-65-3 isoquinoline 
• 98722-14-6 2-(2-(1H-indol-3-yl)ethyl)isoquinolin-1(2H)-one 
• 51598-74-4 2-benzoyl-1-methylene-2,3,4,9-tetrahydro-1H-β-carboline 
• 201230-82-2 carbon monoxide 
• 491-31-6 isocoumarin 
• 61-54-1 tryptamine 
• 14961-34-3 diethyl homophthalate 
• 15868-29-8 1-oxo-1H-isochromene-4-carboxylic acid 

Relevant articles and documents

Base-promoted aerobic oxidation of: N -alkyl iminium salts derived from isoquinolines and related heterocycles

Potassium tert-butoxide-promoted aerobic oxidation of N-alkyl iminium salts is reported. The reaction is atom-economical and environmentally friendly. Iminium salts derived from isoquinoline, quinoline, phenanthridine, phenanthroline, and phthalazine were successfully transformed into their corresponding unsaturated lactams with up to 95% yield under mild conditions in the absence of photocatalysts and metallic or organic catalysts. Owing to the general substrate scope, low cost, feasibility of scale up, wide availability of reagents, and green reaction conditions, this method shows great potential for preparing isoquinolones and related compounds. The method was applied for atom- and step-economical total synthesis of natural products such as norketoyobyrine.

A SIMPLE SYNTHESIS OF YOHIMBAN, ALLOYOHIMBAN, AND ALLOYOHIMBONE BY REDUCTIVE PHOTOCYCLIZATION OF ENAMIDES

A simple synthesis of yohimban (6a) and alloyohimban (6b), and alloyohimbone (10) was achieved by reductive photocyclization of the enamides (1a) and (1b) in the presence of sodium borohydride respectively.