3900-83-2

Basic information

• Product Name: ethyl α-diazo-4-nitrophenylacetate
• Synonyms: ethyl α-diazo-4-nitrophenylacetate
• CAS NO: 3900-83-2
• Molecular Weight: 235.199
• Mol File: 3900-83-2.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: ethyl α-diazo-4-nitrophenylacetate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl α-diazo-4-nitrophenylacetate(3900-83-2)
• EPA Substance Registry System: ethyl α-diazo-4-nitrophenylacetate(3900-83-2)

Safety Data

• Hazardous Substances Data: 3900-83-2(Hazardous Substances Data)

Upstream product

• 623-73-4 diazoacetic acid ethyl ester 
• 636-98-6 p-nitrobenzene iodide 
• 586-78-7 para-nitrophenyl bromide 
• 104-03-0 4-nitrobenzeneacetic acid 
• 941-55-9 4-toluenesulfonyl azide 
• 5445-26-1 ETHYL 4-NITROPHENYLACETATE 
• 2009-97-4 ethyl 2-diazo-3-oxobutanoate 
• 1422530-00-4 C₁₇H₁₇N₃O₆S 
• 121-44-8 triethylamine 
• 70091-75-7 ethyl 2-(4-nitrophenyl)-2-oxoacetate 
• 1334313-52-8 (Z)-ethyl 2-(4-nitrophenyl)-2-(2-tosylhydrazono)acetate 

Downstream Products

• 1254332-51-8 C₁₀H₁₀NO₈P^(2-) 
• 1334313-83-5 ethyl 2-methoxy-2-(4-nitrophenyl)acetate 
• 1398181-08-2 ethyl 3,3,3-trifluoro-2-(4-nitrophenyl)propanoate 
• 1422529-96-1 ethyl 2-(dimethoxyphosphoryl)-2-(4-nitrophenyl) acetate 
• 1451218-34-0 ethyl 2-(4-chlorophenylamino)-2-(4-nitrophenyl)acetate 
• 92-52-4 biphenyl 
• 4691-72-9 ethyl α-bromo-p-nitrophenylacetate 

Relevant articles and documents

Electrochemical two-electron oxygen reduction reaction (ORR) induced aerobic oxidation of α-diazoesters

Electrochemical oxygen reduction reaction (ORR) is a powerful tool for introducing oxygen functional groups in synthetic chemistry. However, compared with the well-developed one-electron oxygen reduction process, the applications of two-electron oxygen re

Synthesis of Rhodium Complexes with Chiral Diene Ligands via Diastereoselective Coordination and Their Application in the Asymmetric Insertion of Diazo Compounds into E?H Bonds

A new method for the synthesis of chiral diene rhodium catalysts is introduced. The readily available racemic tetrafluorobenzobarrelene complexes [(R2-TFB)RhCl]2 were separated into two enantiomers via selective coordination of one of them with the auxiliary S-salicyl-oxazoline ligand. One of the resulting chiral complexes with an exceptionally bulky diene ligand [(R,R-iPr2-TFB)RhCl]2 was an efficient catalyst for the asymmetric insertion of diazoesters into B?H and Si?H bonds giving the functionalized organoboranes and silanes with high yields (79–97 %) and enantiomeric purity (87–98 % ee). The stereoselectivity of separation via auxiliary ligand and that of the catalytic reaction was predicted by DFT calculations.

Photochemical Doyle-Kirmse Reaction: A Route to Allenes

This Letter describes the metal-free, blue-light-induced [2,3]-sigmatropic rearrangement of sulfonium ylides generated from donor/acceptor diazoalkanes and propargyl sulfides. The reaction furnishes highly functionalized allenes from a broad range of starting materials in decent yield. Mechanistic experiments supported by the literature data suggest singlet carbenes as intermediates in this reaction.